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化工学报  2015 

金属有机框架MIL-100(Cr)和MIL-101(Cr)负载磷钨酸催化合成双酚F

DOI: 10.11949/j.issn.0438-1157.20141068, PP. 576-583

Keywords: 金属有机框架,载体,磷钨酸,催化(作用),双酚F,合成

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Abstract:

采用两种具有相同拓扑结构而孔道不同的金属有机框架MIL-100(Cr)和MIL-101(Cr)负载磷钨酸(PTA),通过XRD、BET、FT-IR、TEM和ICP的对比测试分析,对它们负载磷钨酸前后及其不同负载量情况下的各种物化性质进行表征,并用于催化苯酚、甲醛合成双酚F。实验结果表明,在相同的W/Cr投料摩尔比下,MIL-100(Cr)的磷钨酸负载量大于MIL-101(Cr)的磷钨酸负载量;当MIL-100(Cr)负载磷钨酸的W/Cr摩尔比为0.40时(磷钨酸负载量16.47%),其催化活性最好,双酚F收率和选择性分别达93.18%和96.11%,反应0.5h双酚F4,4'-位异构体比例高达74.24%,催化剂重复使用6次仍保持较高催化活性。

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