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聚乙烯与水反应的高温高压实验及热力学探讨

DOI: 10.11858/gywlxb.2001.03.002, PP. 169-177

Keywords: 聚乙烯,,高压荧光,气相色谱,热力学

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Abstract:

在金刚石压腔设备中进行聚乙烯的高温高压裂解实验研究。实验分含水和不含水两种情况。在显微镜下观察反应过程中的变化并显微照相记录有关现象,在高压下就位测定反应过程中荧光的变化。用气相色谱方法测定气相产物组成。含水实验中CH4占烃类气体产物的92%并有CO2生成,固体残余物非常少,表明水直接参与了化学反应,为烃类气体的形成提供氢源,为CO2的形成提供氧源。不含水实验中烃类气体的产率相对较低并有较多的固相残余物存在。用热力学理论探讨了实验中有关反应的机制。根据聚乙烯与干酪根结构的可比性,推测在水参与条件下有利于提高有机质裂解成烃的产率。

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