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高压下纳米尺寸Sr2FeMoO6粉末的结构稳定性和电学特性的研究

DOI: 10.11858/gywlxb.2004.03.001, PP. 193-197

Keywords: 钙钛矿结构,巨磁阻效应,晶界效应

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Abstract:

采用高分子网络凝胶法,通过控制其化学反应过程,合成了高纯的多晶纳米级粉末Sr2FeMoO6样品A(50nm)和样品B(100nm)。对其在高压下的结构稳定性和电学性质进行了研究,并将样品A和样品B的实验结果与已报道的粒度达微米级的块状Sr2FeMoO6样品C的实验结果进行了对比。在实验测量范围内,样品A(50nm)呈现出最大的体弹模量B0,并在电阻-压力曲线中,电阻下降区域表现出相对较缓的变化率,晶界效应可以用来很好地解释此结果。电学性质测量实验表明,样品在高压下发生了电子结构相变。

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