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一种新的氮化碳相的冲击波合成

DOI: 10.11858/gywlxb.2006.01.005, PP. 20-24

Keywords: 氮化碳,冲击波合成,亚稳相

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Abstract:

为了合成理论预测存在的高密度氮化碳相,以富氮的C-N-O非晶材料和晶态的双氰胺为前体,在低于50GPa的冲击压力范围内进行了一系列冲击回收实验。回收产物的XRD衍射表明,形成了由β-C3N4和一种新的氮化碳相组成的复合相。该新相的衍射峰可以完全指标化为一个单斜晶胞,晶胞常数为a=0.981nm,b=0.723nm,c=0.561nm,β=95.2°,晶胞体积Vcell=0.3966nm3。根据实验结果可以认为,氮化碳复合相的形成是前体有机分子在瞬态的冲击波化学反应后,经历了极高速的冲击淬火过程(约109K/s),作为一种高压亚稳相而被保存下来。冲击压缩富氮的有机物前体,是合成氮化碳相的一种新方法。

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