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新型含能富勒烯衍生物的合成研究

DOI: 10.11858/gywlxb.2006.02.019, PP. 220-224

Keywords: N-甲基甘氨酸,2,4-二硝基苯甲醛,C60,含能富勒烯,合成工艺

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Abstract:

利用N-甲基甘氨酸、2,4-二硝基苯甲醛和C60反应,合成分离出了含有两个硝基的新型富勒烯吡咯烷衍生物1,并对其工艺条件进行了研究,探讨了反应物剂量比、温度和时间对产物1产率的影响,得到了合成产物1的最佳工艺条件:反应物剂量比为1∶2∶6、温度为95℃、反应时间为40h,此时产物1产率可达到65.8%(以消耗的C60计)。同时用1HNMR、FT-IR、MS、UV-Vis等光谱手段确定了产物1的分子结构。

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