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MgO单晶冲击变形产生点缺陷吸收谱的实时测量

DOI: 10.11858/gywlxb.2014.06.008, PP. 691-698

Keywords: MgO单晶,冲击塑性,色心吸收,点缺陷

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Abstract:

为研究冲击塑性变形产生的缺陷对MgO单晶透明性的影响,采用40通道(波长)纳秒时间分辨高温计和冲击波原位光源技术,对在一维应变冲击加载下MgO单晶的透射谱进行了实验测量。冲击波加载方向垂直于样品(100)晶面,测谱范围为400~800nm,得到了2个压力点(约50GPa和约70GPa)的吸收系数随波长的变化曲线,从实测曲线发现了6个明显的特征吸收峰,其中心波长分别为410、460、490、520、580和660nm。通过对比分析,确定出410、460、490和580nm处的吸收峰为F聚心吸收,520nm处的吸收峰为V-心吸收,而660nm处的吸收峰则可能为与填隙原子相关的吸收。这是在冲击压缩条件下,首次实时观测到的MgO单晶样品冲击塑性变形产生的点缺陷色心吸收现象。

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