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NH4HCO3溶液中PAN-基碳纤维电化学改性机理

, PP. 22-27

Keywords: 电化学处理,PAN-基碳纤维,表面改性,NH4HCO3

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Abstract:

采用循环伏安扫描法和XPS、AFM技术对在NH4HCO3溶液中经过电化学改性处理的PAN-基碳纤维的电化学特性、表面化学构成和表面形貌变化进行了分析。结果表明,在NH4HCO3溶液中纤维表面主要发生了水的电解析氧反应和部分电活性物质的电化学氧化反应;纤维表面各含氧官能团含量随处理时间的延长不断变化,NH+4与纤维表面官能团反应使纤维表面引入大量的酰胺基团;纤维表面形貌在点蚀和气动剥蚀效应的联合作用下不断粗化。

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