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纳米SiO2对聚丙烯酸酯复合涂层在水润滑下摩擦学性能的影响

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Keywords: 纳米SiO2,聚丙烯酸酯,涂层,摩擦学性能,水润滑

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Abstract:

考察了纳米SiO2对聚丙烯酸酯复合涂层在水润滑下摩擦磨损性能的影响。利用FTIR分析纳米SiO2与聚丙烯酸酯的界面结合;利用SEM观察复合涂层磨损表面,并结合FTIR和摩擦磨损实验分析其磨损机理。结果表明:水润滑时,聚丙烯酸酯在摩擦过程中会发生摩擦化学反应,引起涂层摩擦腐蚀磨损;而纳米SiO2能与聚丙烯酸酯以化学键的形式结合,它的加入有助于摩擦界面在水介质中形成具有较好减摩作用的表面膜和水分子膜,提高聚丙烯酸酯复合涂层的耐磨性。在水润滑下,当纳米SiO2的含量较低时,涂层表面的磨损形式为摩擦腐蚀磨损和磨粒磨损;当纳米SiO2的含量达到5wt%时,涂层表面形成完整的表面膜和水分子膜,此时涂层具有良好的摩擦学性能。

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