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长江流域河水和悬浮物的锂同位素地球化学研究

DOI: 10.11867/j.issn.1001-8166.2008.09.0952, PP. 952-958

Keywords: 锂同位素,同位素分馏,粘土矿物,化学风化,来源

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Abstract:

深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成(δ7Li)分别为150~4570nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成(δ7Li)变化比较稳定,分别为41~92μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。

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