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CaCO3生物矿化的研究进展——有机质的控制作用

DOI: 10.11867/j.issn.1001-8166.2000.02.0204, PP. 204-209

Keywords: 生物CaCO3,有机质,结晶控制,分子识别

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Abstract:

生物CaCO3是自然界分布最广泛的一类生物矿物,其组成除了无机相的CaCO3外,还含有少量的有机质,包括水可溶(SM)和水不可溶有机质(IM),SM富含阴离子基团,是控制CaCO3结晶的重要因素之一。通过有机—无机界面分子识别,有机质选择性地与CaCO3晶体特定方向的面网相互作用,从而对CaCO3的生长、形貌、多型及结晶学定向等产生明显的控制作用。有机—无机界面的分子识别机制包括静电、晶格几何匹配和立体化学互补等。仿生矿化的研究为进一步深入了解生物矿化的机理及制造高级复合材料提供了新的方法。

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