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榍石:U-Pb定年及变质P-T-t轨迹的建立

, PP. 1258-1267

Keywords: 榍石,变质反应,U-Pb定年,榍石温压计,P-T-t轨迹

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Abstract:

榍石在各类岩石中普遍存在,其稳定性受全岩成分、氧逸度和水活度以及温度和压力等因素影响。它在岩浆岩中主要存在于高Ca/Al比值的岩石中,在变质岩中常见于绿片岩相、蓝片岩相和角闪岩相岩石,在钙质变质岩中其稳定范围可达榴辉岩相或高压麻粒岩相。一般榍石结构中U含量较高,且具有高达高角闪岩相上限的U-Pb同位素体系封闭温度,是理想的U-Pb定年矿物。由于榍石的组成元素均为岩石中的主要元素,很容易与其它矿物、熔体及流体发生反应,所以榍石的U-Pb年龄记录的更可能是结晶年龄,而不是简单的扩散重置年龄;也因为它容易反应,变质榍石复杂的U-Pb体系可能记录了岩石的整个变质历史信息。通过与榍石平衡共生的矿物组合或利用榍石Zr温压计可确定岩石的P-T条件,结合相关的榍石年龄信息即可建立变质过程的P-T-t轨迹。利用SHRIMP、LA-MC-ICP-MS以及LA-ICP-MS方法可对不均一榍石颗粒内部进行原位微区分析得到有意义的U-Pb年龄;利用榍石中Zr含量对温度,尤其是对压力比较敏感,可建立榍石Zr含量温压计。

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