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地理科学  2009 

向日葵根分泌物对针铁矿吸附Cd2+的抑制效应

, PP. 455-460

Keywords: 针铁矿,,吸附,根分泌物

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Abstract:

向日葵根分泌物明显抑制针铁矿吸附Cd2+。随着pH的升高,针铁矿对Cd2+的吸附量升高,针铁矿对Cd2+的平衡吸附量pH在3~6时增长的幅度较大,pH>7后,对Cd2+的吸附量的增长趋于稳定。在溶液初始pH为3~8的范围内,向日葵根分泌物抑制针铁矿对Cd2+的吸附。针铁矿等温吸附Cd2+符合Langmuir方程和Freundlich方程,吸附动力学符合二级速率方程。根分泌物的存在明显抑制针铁矿对Cd2+的吸附强度和吸附速率。表明针铁矿对Cd2+的吸附是一个熵增的吸热反应;根分泌物的存在则降低了吸附反应的自发性。

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