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地理科学  2012 

海岸带盐沼挥发性氯代烷烃单体成分通量的相互关系

, PP. 213-218

Keywords: 氯代烷烃,相互关系,海岸带盐沼

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Abstract:

挥发性氯代烷烃是大气中重要的短命氯源气体,对全球气候变暖和臭氧层破坏具有重要贡献,在全球C和Cl元素循环中扮演着重要的角色,具有非常重要的环境意义。分别于生长季(2004年7月)和非生长季(2005年1月)在苏北海岸带盐沼沿环境梯度采用静态箱技术原位测定氯代甲烷(CH3Cl、CH2Cl2、CHCl3和CCl4)和氯代乙烷(CH3CHCl2和CH3CCl3)6种单体成分通量。结果表明海岸带盐沼生态系统氯代烷烃单体成分通量关系的差异性主要表现在3个方面一是海岸带盐沼高氯烷烃不同单体成分间具有很好的相关性,而低氯烷烃CH3Cl与各种高氯烷烃单体成分间相关性不显著。这表明海岸带盐沼低氯烷烃和高氯烷烃的源汇过程可能是不同的,而高氯烷烃间可能存在比较一致的源汇过程;二是高等植物对氯代烷烃不同单体成分贡献的差异性表现为对低氯烷烃CH3Cl表现为源效应,而对高氯烷烃则表现为汇效应;三是盐沼土壤对氯代烷烃不同单体成分的贡献均表现为汇效应,但是研究区低氯烷烃和高氯烷烃来源和生物降解模式不同。低氯烷烃CH3Cl可能源于盐沼植物及其枯落物排放和海洋排放的输入,而高氯烷烃含量既可能来自非生长季盐沼植物和凋落...

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