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煤储层中水的成因、年龄及演化:卤素离子、稳定同位素和129I的证据

, PP. 1699-1707

Keywords: 地层水,卤素离子,稳定同位素,129I/127I,测年,演化过程

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Abstract:

?石炭-二叠系煤层是鄂尔多斯盆地韩城煤层气田的主力产层,煤层中水的特征对于煤层气富集的研究有着重要的意义.本文通过采集研究区煤层气井的水样,利用加速器质谱仪(AMS)测得地层水中的放射性同位素129I信息,结合卤素离子浓度和稳定氢氧同位素特征,对石炭-二叠系煤层中水的来源、年龄和演化过程进行了探讨.研究结果表明,煤层中水的矿化度为1532.29~7061.12mg/L,属于中低矿化度水,水型以NaHCO3和NaCl水为主,129I和I/Cl值指示其经历了稀释-混合作用.地层水129I/127I的比值分布在660×10-15~145950×10-15,多数介于129I初始值和现今大气降水的129I水平之间,计算的地层水的年龄为0~18.50Ma.研究区石炭-二叠系煤层中水有两个来源,一部分为古大气降水(中新世),特征为δD和δ18O值在全球大气降水线下方,低129I/127I值;另一部分为现代混合水,特征为较高的129I/127I值.结合地质过程,推测地层水经历了沉积水→沉积水、成岩水→古大气降水、现代混合水的演化过程.

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