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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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含1,8-萘酰亚胺单元的咔唑磺酰肼受体的合成及对阴离子的识别研究有机化学
DOI: 10.6023/cjoc201407012, PP. 2499-2504
Keywords: 咔唑,磺酰肼,1,8-萘酰亚胺,阴离子识别
Abstract:
设计合成了一个新型的含1,8-萘酰亚胺信号单元的咔唑磺酰肼类阴离子受体1,荧光和UV-vis光谱滴定实验表明,1在DMSO中能选择性识别具有重要生物学意义的F-,AcO-和H2PO4-;受体1与这些阴离子形成1:1的配合物,且它们的结合常数均大于103L·mol-1.有趣的是,在含水10%(V/V)的DMSO中1对F-表现出了专一性识别.DMSO-d6中的核磁滴定表明,在F-浓度较低时,受体1通过五重分子间氢键作用与其产生了有效结合.
| [1] | McDonagh, C.; Burke, C. S.; MacCraith, B. D. Chem. Rev. 2008, 108, 400.
|
| [2] | Kirk, K. L. Biochemistry of the Halogens and Inorganic Halides, Plenum Press, New York, 1991.
|
| [3] | Choudhary, C.; Kumar, C.; Gnad, F.; Nielsen, M. L.; Rehman, M.; Walther, T. C.; Olsen, J. V.; Mann, M. Science 2009, 325, 834.
|
| [4] | Liu, Y.; Zhang, F.; Zou, L.; Jian, J.; Bao, X. Chin. J. Org. Chem. 2013, 33, 2485 (in Chinese). (刘勇, 张峰, 邹林波, 蹇军友, 鲍小平, 有机化学, 2013, 33, 2485.)
|
| [5] | Sun, Y.; Zhong, C.; Gong, R.; Fu, E. Org. Biomol. Chem. 2008, 6, 3044.
|
| [6] | Luo, X.; Qian, Y. Chin. J. Org. Chem. 2013, 33, 2423 (in Chinese). (罗晓燕, 钱鹰, 有机化学, 2013, 33, 2423.)
|
| [7] | Bao, X.; Zhou, Y.; Song, B. Sens. Actuators B 2012, 171～172, 550.
|
| [8] | De Silva, A. P.; Gunaratne, H. Q. N.; Gunnlaugsson, T.; Huxley, A. J. M.; McCoy, C. P.; Rademacher, J. T.; Rice, T. E. Chem. Rev. 1997, 97, 1515.
|
| [9] | Valeur, B.; Pouget, J.; Bourson, J.; Kaschke, M.; Ernsting, N. P. J. Phys. Chem. 1992, 96, 6545.
|
| [10] | Schneider, H. J.; Kramer, R.; Simova, S.; Schneider, U. J. Am. Chem. Soc. 1988, 110, 6442.
|
| [11] | Liu, S.-Y.; Fang, L.; He, Y.-B.; Chan, W.-H.; Yeung, K.-T.; Cheng, Y.-K.; Yang, R.-H. Org. Lett. 2005, 7, 5825.
|
| [12] | Beer, P. D.; Gale, P. A. Angew. Chem., Int. Ed. 2001, 40, 486.
|
| [13] | Ayoob, S.; Gupta, A. K. Crit. Rev. Environ. Sci. Technol. 2006, 36, 433.
|
| [14] | Adams, R. L. P.; Knowler, J. T.; Leader, D. P. The Biochemistry of the Nucleic Acids, 10th ed, Chapman and Hall, New York, 1986.
|
| [15] | Bao, X.-P.; Wang, L.; Wu, L.; Li, Z.-Y. Supramol. Chem. 2008, 20, 467.
|
| [16] | Veale, E. B.; Gunnlaugsson, T. J. Org. Chem. 2008, 73, 8073.
|
| [17] | Bao, X.; Yu, J.; Zhou, Y. Sens. Actuators B 2009, 140, 467.
|
| [18] | Bao, X.-P.; Zhou, Y.-H.; Yu, J.-H. J. Lumin. 2010, 130, 392.
|
| [19] | Bao, X. P.; Zheng, P. C.; Liu, Y.; Tan, Z.; Zhou, Y. H.; Song, B. A. Supramol. Chem. 2013, 25, 246.
|
| [20] | Boiocchi, M.; Boca, L. D.; Gómez, D. E.; Fabbrizzi, L.; Licchelli, M.; Monzani, E. J. Am. Chem. Soc. 2004, 126, 16507.
|
| [21] | Bourson, J.; Pouget, J.; Valeur, B. J. Phys. Chem. 1993, 97, 4552.
|
| [22] | Wu, F.-Y.; Li, Z.; Wen, Z.-C.; Zhou, N.; Zhao, Y.-F.; Jiang, Y.-B. Org. Lett. 2002, 4, 3203.
|
| [23] | Upadhyay, K. K.; Mishra, R. K.; Kumar, V.; Chowdhury, P. K. R. Talanta 2010, 82, 312.
|
| [24] | Fuentes de Arriba, á. L.; Turiel, M. G.; Simón, L.; Sanz, F.; Boyero, J. F.; Mu？iz, F. M.; Morán, J. R.; Alcázar, V. Org. Biomol. Chem. 2011, 9, 8321.
|
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