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有机化学  2012 

新颖的银(I)催化磺酰氯与芳香端炔的反应有机化学

DOI: 10.6023/cjoc201204011, PP. 1872-1879

Keywords: 炔烃,磺酰氯,烯基砜,银盐,炔基银

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Abstract:

报道银(I)催化芳香端炔与磺酰氯的新颖反应.该反应出乎意料地得到烯基砜,产率47%~72%,并且具有Z选择性.提出了自由基催化循环机理,解释了烯基砜的形成及烯基砜的立体化学结果.

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