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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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无碱参与的铜催化芳基硼酸和硫酚的偶联反应研究有机化学
DOI: 10.6023/cjoc201209008, PP. 343-347
Keywords: 偶联反应,硫酚,芳基硼酸,1,10-菲啰啉,醋酸铜
Abstract:
无碱参与的条件下,研究了Cu盐催化芳基硼酸与硫酚的偶联反应.通过反应溶剂、温度、铜盐、配体等条件的优化,结果表明在空气中,以1,10-菲啰啉-醋酸铜为催化剂,DMSO/H2O(V:V＝1:1)作为溶剂,反应温度为60℃,以较高产率合成二芳基硫醚.
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