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OALib Journal期刊
ISSN: 2333-9721
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氯化铯催化羧酸钠(钾)与α-氯代乙酸酯及溴(氯)代烃反应有机化学
DOI: 10.6023/cjoc201208010, PP. 190-194
Keywords: 氯化铯,羧酸钠钾,α-氯代乙酸酯,酯化反应
Abstract:
以DMF为溶剂,在催化量氯化铯存在下,羧酸钠(钾)与α-氯代乙酸酯在室温下反应及其与溴(氯)代烃在60℃反应,分别形成对应的羧酸(α-烷氧甲酰)甲酯与羧酸酯,产率90%以上,讨论了催化机理.
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