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OALib Journal期刊
ISSN: 2333-9721
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超临界二氧化碳介质中端炔C—H键与CO2的羧化反应研究有机化学
DOI: 10.6023/cjoc201403064, PP. 2172-2177
Keywords: 醋酸银,1,8-二氮杂二环十一碳-7-烯,端炔,超临界二氧化碳,羧化反应
Abstract:
建立了一个不使用有机溶剂的端炔C—H键羧化新体系：在Ag（I）/DBU（1，8-二氮杂二环十一碳-7-烯）催化体系中，通过超临界二氧化碳与端基炔的羧化反应，以较高产率得到了相应丙炔酸产物.在反应体系中，超临界二氧化碳既是反应物又是反应溶剂；助剂DBU起到了碱、亲核体和共催化剂的作用，并能够明显加快反应速率.筛选出的催化体系具有良好的催化反应活性和底物适应能力，能够实现液态、固态端基炔与超临界二氧化碳的直接羧化反应，为制备功能化丙炔酸类化合物提供了一个环境友好、简单、经济的合成路线.
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