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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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可溶液加工p-n多臂结构共轭分子的设计合成与应用有机化学
DOI: 10.6023/cjoc201405016, PP. 2027-2034
Keywords: p-n共轭分子,多臂结构分子,可溶液加工,光电转换
Abstract:
设计合成了两种以p型苯基咔唑为核，n型苯并噻二唑衍生物为臂的p-n多臂结构共轭分子S1和S2.通过1HNMR，13CNMR，GC-MS/MALDI-TOF等表征了其化学结构，研究了其光物理性质、热力学性质、电化学性质及其电子结构等，并作为活性材料应用于制备有机太阳能电池器件.实验结果表明所得的p-n多臂结构共轭分子表现出良好的溶液加工性、较宽的光谱吸收、较窄的能隙和较高的开路电压等特性.
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