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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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离子液体中钯催化合成cis-1,2-二卤代-1,7-辛二烯的反应研究有机化学
DOI: 10.6023/cjoc201401017, PP. 1148-1153
Keywords: 离子液体,钯催化,炔卤,5-己烯-1-醇,cis-1,2-二卤代烯烃
Abstract:
发展了一种以PdBr2为催化剂，以[Bmim]X/HXaq为溶剂，炔卤与5-己烯-1-醇进行交叉偶联反应的新方法，以中等及优良的产率（73%～94%）合成了系列cis-1，2-二卤代-1，7-辛二烯衍生物.反应表现出较高的区域选择性和立体选择性.并且该偶联反应合成途径简捷、反应条件温和，可为cis-1，2-二卤代烯烃类化合物的合成提供简便的途径.
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