OALib Journal期刊
银催化炔丙醇与芳基异腈交叉偶联反应:原子经济性合成N-芳基-2,3-联烯酰胺有机化学
DOI: 10.6023/cjoc201505025
Keywords: 丙炔醇 ,芳基异腈 ,碳酸银 ,交叉偶联反应
Abstract:
炔丙醇和芳基异氰在银催化条件下能够发生交叉偶联反应,高产率地生成N-芳基-2,3-联烯酰胺.该反应具有条件温和、原子经济性和底物范围宽泛等优点,多种芳基异腈和炔丙醇均能发生交叉偶联反应,并生成相应的N-芳基-2,3-联烯酰胺.该方法解决了前期工作中异腈种类受限的问题,为合成N-芳基联烯酰胺提供了简便新途径.
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