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OALib Journal期刊
ISSN: 2333-9721
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铜纳米颗粒催化的炔、二卤甲烷、胺三组分偶联反应研究有机化学
DOI: 10.6023/cjoc201412045, PP. 827-834
Keywords: 铜纳米颗粒,AHA偶联反应,炔丙胺,催化剂循环
Abstract:
以铜纳米颗粒作为催化剂,Cs2CO3为碱,二卤甲烷为底物和溶剂,发展了一个高效的催化炔、二卤甲烷、胺三组分偶联反应(AHA偶联反应)生成炔丙胺的反应体系.与文献相比,该催化体系具有催化剂廉价易得、反应条件相对温和、底物适应性优良、使用单一溶剂体系后处理方便的特点.同时,以铜纳米颗粒为催化剂,易于实现催化剂的有效循环利用,经5次反应催化活性未见明显下降.
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