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有机化学  2015 

光照条件下链状醚α-碳-氢键官能团化反应研究有机化学

DOI: 10.6023/cjoc201405039, PP. 246-250

Keywords: 光化学,碳-氢键官能团化,机理,自由基反应,绿色化学

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Abstract:

发展了一套新型的可以实现链状醚α-碳-氢键官能团化的方法.该方法无需任何添加剂,仅在紫外光的激发下,室温下即可温和且高效地完成芳基醛、酮类化合物与链状醚类化合物的加成反应,从而可以清洁且高选择性地生成β-羟基醚类化合物.研究了激发光能量及反应温度对该反应的影响,并对该反应可能的机理进行了讨论.

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