Flow Rate and Interference Studies for Copper Binding to a Silica-Immobilized Humin Polymer Matrix: Column and Batch Experiments

Batch and column experiments were performed to determine the Cu(II) binding capacity of silica-immobilized humin biomass. For column studies, 500 bed volumes of a 0.1 mM Cu(II) solution were passed through humin packed columns at the flow rates of 1, 1.5, 2, and 3 mL/min. The biopolymer showed an average Cu binding capacity of 12 ± 1.5 mg/g and a Cu recovery of about 96.5 % ± 1.5. The breakthrough points for Cu(II) alone were approximately 420, 390, 385, and 300 bed volumes for the flow rates of 1, 1.5, 2 and 3 mL/min, respectively. The interference studies demonstrated that at low concentrations, the hard cations Ca(II) and Mg(II) did not seem to represent a major interference on Cu(II) binding to the humin biopolymer. The selectivity showed by this biopolymer was Cu(II)>Ca(II)>Mg(II). On the other hand, batch experiments showed that Ca(II)