全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Leather Industry Solid Waste as Nitrogen Source for Growth of Common Bean Plants

DOI: 10.1155/2010/703842

Full-Text   Cite this paper   Add to My Lib

Abstract:

The leather industry generates large amounts of a Cr-containing solid waste (wet blue leather). This material is classified by the Brazilian Environmental Council as a category-one waste, requiring a special disposal. The patented process Br n. PI 001538 is a technique to remove chromium from wet blue leather, with the recovery of a solid collagenic material (collagen), containing high nitrogen levels. This work aimed to evaluate the residual effect of soil application of collagen on the production of dry matter, content and accumulation of N in common bean plants (Phaseolus vulgaris L.), after the previous growth of elephantgrass (Pennisetum purpureum Schumach.) cv. Napier, as well as to quantify the mineralization rate of N in the soil. The application of collagen, at rates equivalent to 16 and 32?t? , provided greater N contents in the common bean plants, indicating residual effect of these rates of application; the same was observed for the rates of 4 and 8?t? , though in smaller proportions. Higher mineralization rates of N collagen occurred next to 16 days after soil incubation. During the 216 days of incubation, the treatments with collagen showed higher amounts of mineralized nitrogen. 1. Introduction The production of leather industry solid wastes has increased and the use of such wastes as fertilizers represents an interesting alternative for their disposal, with less potential impact to the environment [1]. The production of chromium-containing solid waste in tanneries has been recognized as a problem for many years,and increasing pressure from environmental authorities has demanded a solution of such a problem [2]. Historically, shavings, trimmings, and splits from the chromium tanning of hides and skins have been disposed of in landfills. However, increasing local restrictions on land disposal and the high costs of incineration have stimulated the search for alternative treatments. Many scientific groups have oriented their research to find a process to recycle and treat these wastes [3–11]. In Brazil, some research was carried out to evaluate the effect of leather industry works in the growth of cultures of commercial interest [12–15]. Castilhos et al. [13] evaluated the yields of wheat, lettuce, and radish, as well as the chemical changes in an Oxisol due to the addition of tannery wastes (primary tannery sludge; chromium-tanned leather shavings; finished leather shreds). Yields of the three crops in microplots treated with the wastes were similar to that obtained in microplots treated with lime plus NPK. Chromium concentrations in the

References

[1]  L. C. A. Oliveira, R. M. Dallago, and I. Nascimento Filho, “Processo de reciclagem dos resíduos sólidos de curtumes por extra??o do cromo e recupera??o do couro descontaminado,” Br PI 001538, 2004.
[2]  A. Gammoun, S. Tahiri, A. Albizane, M. Azzi, J. Moros, S. Garrigues, and M. de la Guardia, “Separation of motor oils, oily wastes and hydrocarbons from contaminated water by sorption on chrome shavings,” Journal of Hazardous Materials, vol. 145, no. 1-2, pp. 148–153, 2007.
[3]  H. Rosentreter, H. G. Klein, B. Wehling, and B. Makowka, “Processo de curtimento ao cromo de couros descarnados e depilados piquelados,” Br Pi 8804055, 1988.
[4]  M. K. Compassi, “Processo de dissolu??o termo-química de serragem e/ou retalhos e aparas de couros curtidos ao cromo,” Br PI 9202408, 1992.
[5]  E. M. Brown, M. M. Taylor, and W. N. Marmer, “Production and potential uses of co-products from solid tannery waste,” Journal of the American Leather Chemists Association, vol. 91, no. 10, pp. 270–276, 1996.
[6]  L. F. Cabeza, M. M. Taylor, and M. M. Taylor, “Treatment of sheepskin chrome shavings. Isolation of high value protein products and reuse of chromium in the tanning process,” Journal of the American Leather Chemists Association, vol. 94, no. 7, pp. 268–287, 1999.
[7]  I. C. T. Silveira, D. Rosa, L. O. Monteggia, G. A. Romeiro, E. Bayer, and M. Kutubuddin, “Low temperature conversion of sludge and shavings from leather industry,” Water Science and Technology, vol. 46, no. 10, pp. 277–283, 2002.
[8]  C. Mu, W. Lin, M. Zhang, and Q. Zhu, “Towards zero discharge of chromium-containing leather waste through improved alkali hydrolysis,” Waste Management, vol. 23, no. 9, pp. 835–843, 2003.
[9]  S. P. B. Kamaludeen, K. R. Arunkumar, S. Avudainayagam, and K. Ramasamy, “Bioremediation of chromium contaminated environments,” Indian Journal of Experimental Biology, vol. 41, no. 9, pp. 972–985, 2003.
[10]  B. Rivela, M. T. Moreira, C. Bornhardt, R. Méndez, and G. Feijoo, “Life cycle assessment as a tool for the environmental improvement of the tannery industry in developing countries,” Environmental Science and Technology, vol. 38, no. 6, pp. 1901–1909, 2004.
[11]  S. Saravanabhavan, P. Thanikaivelan, J. R. Rao, B. U. Nair, and T. Ramasami, “Natural leathers from natural materials: progressing toward a new arena in leather processing,” Environmental Science and Technology, vol. 38, no. 3, pp. 871–879, 2004.
[12]  E. E. Konrad and D. D. Castilhos, “Altera??es químicas do solo e crescimento do milho decorrentes da adi??o de lodos de curtume,” Revista Brasileira de Ciência, Vi?osa, vol. 26, pp. 257–265, 2002.
[13]  D. D. Castilhos, M. J. Tedesco, and C. Vidor, “Rendimentos de culturas e altera??es químicas do solo tratado com resíduos de curtume e cromio hexavalente,” Revista Brasileira de Ciência do Solo, Vi?osa, vol. 26, pp. 1083–1092, 2002.
[14]  V. Aquino Neto and O. A. Camargo, “Crescimento e acúmulo de cr?mio em alface cultivada em dois latossolos tratados com e resíduo de curtume,” Revista Brasileira de Ciência do Solo, Vi?osa, vol. 24, pp. 255–235, 2000.
[15]  R. H. S. Daudt, C. Gruszynski, and A. N. K?mpf, “The use of residues of wet blue leather as a growing media component,” Ciencia Rural, vol. 37, no. 1, pp. 91–96, 2007.
[16]  Conama, “Conselho Nacional Do Meio Ambiente,” Brasília: Resolu??o no. 357, 1. Diário Oficial 17.05.2005 Ofício no 88.351/83, 2005.
[17]  R. Aravindhan, B. Madhan, J. R. Rao, B. U. Nair, and T. Ramasami, “Bioaccumulation of chromium from tannery wastewater: an approach for chrome recovery and reuse,” Environmental Science and Technology, vol. 38, no. 1, pp. 300–306, 2004.
[18]  D. Q. L. De Oliveira, K. T. G. Carvalho, A. R. R. Bastos, L. C. A. De Oliveira, J. J. G. De Sá e Melo Marques, and R. S. De Melo Pereira do Nascimento, “Utiliza??o de resíduos da indústria de couro como fonte nitrogenada para o capim elefante,” Revista Brasileira de Ciencia do Solo, vol. 32, no. 1, pp. 417–424, 2008.
[19]  EMBRAPA (Empresa Brasileira de Pesquisa Agropecuária), Manual de Métodos de Análise de Solos, Ministério da Agricultura e Abastecimento, Rio de Janeiro, Brasil, 1997.
[20]  A. Mehlich, Determination of P, Ca, Mg, K, Na and NH4, North Carolina Soil Test Division, Raleigh, NC, USA, 1953.
[21]  USEPA—United States Environmental Protection Agency, “Method 3051 A: micro-wave assisted acid digestion of sediments sludges, soils and oils,” in Test Methods for Evaluation Solid Waste Physical and Chemical Methods, vol. 846, pp. 1–20, Office of Solid Waste, US Environmental Protection Agency, Washington, DC, USA, 1988.
[22]  EMBRAPA (Empresa Brasileira de Pesquisa Agropecuária), Sistema Brasileiro de Classifica??o de Solos, Ministério da Agricultura e Abastecimento, Rio de Janeiro, Brasil, 1999.
[23]  E. Malavolta, Elementos de Nutri??o Mineral de Plantas, Ceres, S?o Paulo, Brazil, 1980.
[24]  E. Malavolta, G. C. Vitti, and S. A. Oliveira, Avalia??o do Estado Nutricional das Plantas: Princípios e Aplica??es, Potafos, Piracicaba, Brazil, 2nd edition, 1997.
[25]  D. F. Ferreira, “Análises estatísticas por meio do Sisvar para Windows vers?o 4.0,” pp. 255–258, S?o Carlos, Brasil.
[26]  J. M. Bremner, “Inorganic forms of nitrogen,” in Methods of Soil Analysis. Part. 2, C. A. Black, Ed., pp. 1179–1237, American Society of Agronomy, Madison, Wis, USA, 1965.
[27]  D. D. Castilhos, L. Bortolon, and E. S. Oliveira, “Crescimento, nodula??o e absor??o de nutrientes em soja sob concentra??es crescentes de cromo,” Magistra, Cruz das Almas, vol. 17, pp. 33–37, 2005.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133