The influence of cellulose nano fibers extracted from the fruit of luffa cylindrica (LC) on the tensile, flexural and impact properties of composite materials using poly lactic acid (PLA) processed by micro compounding and injection molding was studied. Preliminary results suggested promising mechanical properties. The impact strength, tensile strength and flexural strength of the composites increased with incorporation of very low content of LC fiber up to 2 wt%. But when the wt of LC fiber in the composite increased (5 wt% and 10 wt%), mechanical strength of the composites reduced probably due to agglomeration of cellulose fibers. However, modulus of composites was enhanced with increase in wt of fiber content in the composites. Before reinforcement, the LC fibers were modified with calcium phosphate in order to explore the possibilities of using these composites in biomedical industries. The novelty of this work is that there is no use of compatiblizer and coupling agent during the processing so that the cost of processing is reduced.
References
[1]
Kalia, S., Dufresne, A., Cherian, B.M., Kaith, B.S., Avérous, L., Njuguna, J., Nassiopoulos, E. (2011) Cellulose-Based Bio- and Nano- composites: A Review. International Journal of Polymer Science, Article ID 837875, 35 p.
[2]
John, M.J. and Thomas, S. (2008) Biofibres and Biocomposites. Carbohydrate Polymers, 71, 343-364.
http://dx.doi.org/10.1016/j.carbpol.2007.05.040
[3]
Zenkiewicz, M. and Richert, J. and Rózański, A. (2010) An Effect of Blow Moulding Ratio on Barrier Properties of Polylactide Nanocomposite Films. Polymer Testing, 29, 251-257.
http://dx.doi.org/10.1016/j.polymertesting.2009.11.008
[4]
Bhatia, A., Gupta, R., Bhattacharya, S. and Choi, H. (2010) Effect of Clay on Thermal, Mechanical and Gas Barrier Properties of Biodegradable Poly(lactic acid)/Poly(butylene succinate) (PLA/PBS) Nanocomposites. International Polymer Processing, 25, 5-14. http://dx.doi.org/10.3139/217.2214
[5]
Martino, V.P., Ruseckaite, R.A., Jiménez, A. and Averous, L. (2010) Correlation between Composition, Structure and Properties of Poly(lactic acid)/Polyadipate-Based Nano-Biocomposites. Macromolecular Materials and Engineering, 295, 551-558. http://dx.doi.org/10.1002/mame.200900351
[6]
Rasala, R.M., Janorkarc, A.V. and Hirta, D.E. (2010) Poly(lactic acid) Modifications. Progress in Polymer Science, 35, 338-356. http://dx.doi.org/10.1016/j.progpolymsci.2009.12.003
[7]
Bledzki, A.K. and Gassan, J. (1999) Composites Reinforced with Cellulose Based Fibres. Progress in Polymer Science, 24, 221-274. http://dx.doi.org/10.1016/S0079-6700(98)00018-5
[8]
Sreekala, M.S., Kumaran, M.G. and Thomas, S. (1997) Green Composites from Natural Rubber and Oil. Journal of Applied Polymer Science, 66, 821-835.
http://dx.doi.org/10.1002/(SICI)1097-4628(19971031)66:5<821::AID-APP2>3.0.CO;2-X
[9]
Mazali, I.O. and Alves, O.L. (2005) Morphosynthesis: High Fidelity Inorganic Replica of the Fibrous Network of Loofa Sponge. Annals of the Brazilian Academy of Sciences, 77, 25-31.
[10]
Kakar, A., Jayamani, E., Heng, S.K., Bakri, M.K.B. and Hamdan, S. (2015) Optimization of Hot Press Compression Molding and Fabrication of Poly Lactic Acid (PLA) Luffa Biocomposites for Biomedical Applications. Australian Journal of Basic and Applied Sciences, 9, 105-112.
[11]
Abdulkhani, A., Hosseinzadeh, J., Ashori, A., Dadashi, S. and Takzare, Z. (2014) Preparation and Characterization of Modified Cellulose Nanofibers Reinforced Polylactic Acid Nanocomposite. Polymer Testing, 35, 73-79.
http://dx.doi.org/10.1016/j.polymertesting.2014.03.002
[12]
Srebrenkoska, V., Gaceva, G.B. and Dimesk, D. (2014) Biocomposites Based on Polylactic Acid and Their Thermal Behavior after Recycling. Macedonian Journal of Chemistry and Chemical Engineering, 33, 277-285.
[13]
Hui, Z.-P., Sudhakara, P., Wang, Y.-Q., Kim, B.-S. and Song, J.-I. (2013) Manufacturing and Mechanical Properties of Sisal Fiber Reinforced Hybrid Composites, Composites Research, 26, 273-278.
http://dx.doi.org/10.7234/composres.2013.26.5.273
[14]
Senawi, R., Alauddin, S.M., Saleh, R.M. and Shueb, M.I. (2013) Polylactic Acid/Empty Fruit Bunch Fiber Biocomposite: Influence of Alkaline and Silane Treatment on the Mechanical Properties. International Journal of Bioscience, Biochemistry and Bioinformatics, 3, 59-61. http://dx.doi.org/10.7763/IJBBB.2013.V3.164
[15]
Parida, C., Dash, S.K. and Das, S.C. (2015) Effect of Fiber Treatment and Fiber Loading on Mechanical Properties of Luffa-Resorcinol Composites. Indian Journal of Materials Science, Article ID: 658064.
[16]
Ramakrishna, S., Mayer, J., Wintermantel, E. and Leong, K.W. (2001) Biomedical Applications of Polymer-Composite Materials: A Review. Composites Science and Technology, 61, 1189-1224.
http://dx.doi.org/10.1016/S0266-3538(00)00241-4