全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Temporal Variation and Concentration Weighted Trajectory Analysis of Lead in PM10 Aerosols at a Site in Central Delhi, India

DOI: 10.1155/2014/323040

Full-Text   Cite this paper   Add to My Lib

Abstract:

Ambient levels of lead (Pb) in PM10 were studied at a site in Central Delhi for the period of one year during day and night. The annual mean concentration of lead has been observed as 625 and 1051?ng/m3 during day and night time, respectively. The seasonal averaged concentrations of Pb have followed the order winter > postmonsoon > summer > monsoon. Highest levels of lead have been observed in winter with 31% samples exceeding the CPCB-NAAQS value as 1000?ng/m3. Lead levels during winter have been found to be 5.7 times higher than in monsoon, which might be attributed to prevailing meteorological conditions and more biomass burning. The low levels of Pb during summer might be attributed to its higher dispersion in the atmosphere. A sharp rise of Pb during postmonsoon might be linked to the local nonpoint sources, more biomass burning, and shifting of boundary layer. However, the higher concentrations of lead were observed during night time in all the seasons of the year as compared to those of the day time. To identify the potential source regions of Pb, Concentration Weighted Trajectories (CWT) have been plotted which showed higher influence of local sources during winter and postmonsoon while showing distant sources during summer. 1. Introduction Among the various air pollutants, particulate matter plays an important role due to its effects on different atmospheric processes such as visibility, atmospheric chemistry, radiative balance, and human health [1, 2]. Trace metals associated with particulate matter may increase manyfold, by natural or anthropogenic sources [3–5]. At elevated concentrations, certain trace metals (Hg, Pb, Sn, Cd, etc.) show toxic effects on living beings [2, 6, 7]. Lead (Pb), as a well-known neurotoxin, shows high level of toxicity on living beings [2] and is the only metal listed in the EPA-NAAQS (http://www.epa.gov/air/criteria.html). Due to its adverse effects on human health, especially on pregnant women and children’s growth and intelligence, study of Pb has been a topic of interest. Anthropogenic activities play a major role for the emission of lead into the atmosphere [8]. Once it enters into the atmosphere, it can be deposited on the surface and resuspended to reenter the atmosphere. Thus, it has high potential to remain in the environment [9, 10]. This could increase human exposure to Pb causing adverse health effects [11]. Lead is released into the atmosphere mainly in the gaseous form during high temperature anthropogenic processes such as metal processing, fuel combustion, nonferrous metal production, or waste

References

[1]  R. R. Dickerson, S. Kondragunta, G. Stenchikov, K. L. Civerolo, B. G. Doddridge, and B. N. Holben, “The impact of aerosols on solar ultraviolet radiation and photochemical smog,” Science, vol. 278, no. 5339, pp. 827–830, 1997.
[2]  V. Mudgal, N. Madaan, A. Mudgal, R. B. Singh, and S. Mishra, “Effect of toxic metals on human health,” The Open Nutraceuticals Journal, vol. 3, pp. 94–99, 2010.
[3]  A. G. Allen, E. Nemitz, J. P. Shi, R. M. Harrison, and J. C. Greenwood, “Size distributions of trace metals in atmospheric aerosols in the United Kingdom,” Atmospheric Environment, vol. 35, no. 27, pp. 4581–4591, 2001.
[4]  S. Yadav and V. Rajamani, “Air quality and trace metal chemistry of different size fractions of aerosols in N-NW India—implications for source diversity,” Atmospheric Environment, vol. 40, no. 4, pp. 698–712, 2006.
[5]  F. Song and Y. Gao, “Size distributions of trace elements associated with ambient particular matter in the affinity of a major highway in the New Jersey-New York metropolitan area,” Atmospheric Environment, vol. 45, no. 37, pp. 6714–6723, 2011.
[6]  R. L. Canfield, C. R. Henderson Jr., D. A. Cory-Slechta, C. Cox, T. A. Jusko, and B. P. Lanphear, “Intellectual impairment in children with blood lead concentrations below 10 μg per deciliter,” The New England Journal of Medicine, vol. 348, no. 16, pp. 1517–1526, 2003.
[7]  IARC (International Agency for Research on Cancer), Complete List of Agents Evaluated and Their Classification, International Agency for Research on Cancer, 2009, http://monographs.iarc.fr/ENG/Classification/index.php.
[8]  P. S. Khillare and S. Sarkar, “Airborne inhalable metals in residential areas of Delhi, India: distribution, source apportionment and health risks,” Atmospheric Pollution Research, vol. 3, no. 1, pp. 46–54, 2012.
[9]  C. S. C. Wong and X. D. Li, “Pb contamination and isotopic composition of urban soils in Hong Kong,” Science of the Total Environment, vol. 319, no. 1–3, pp. 185–195, 2004.
[10]  T. M. Young, D. A. Heeraman, G. Sirin, and L. L. Ashbaugh, “Resuspension of soil as a source of airborne lead near industrial facilities and highways,” Environmental Science and Technology, vol. 36, no. 11, pp. 2484–2490, 2002.
[11]  J. O. Nriagu and J. M. Pacyna, “Quantitative assessment of worldwide contamination of air, water and soils by trace metals,” Nature, vol. 333, no. 6169, pp. 134–139, 1988.
[12]  EPA-454/R-98-006, 1998.
[13]  J. D. Blando and B. J. Turpin, “Secondary organic aerosol formation in cloud and fog droplets: a literature evaluation of plausibility,” Atmospheric Environment, vol. 34, no. 10, pp. 1623–1632, 2000.
[14]  AMAP, “Arctic monitoring and assessment programme assessment report,” Arctic Pollution Issues, Arctic Monitoring and Assessment Programme, Oslo, Norway, 1998, http://www.amap.no/.
[15]  K. S. V. Nambi, R. Raghunath, R. M. Tripathi, and R. N. Khandekar, “Scenario of Pb pollution and children in Mumbai: current air quality standard vindicated,” Energy and Environment, vol. 13, pp. 53–60, 1997.
[16]  C. A. Pope and D. W. Dockery, “Health effects of fine particulate air pollution: lines that connect,” Journal of the Air and Waste Management Association, vol. 56, no. 6, pp. 709–742, 2006.
[17]  B. Forsberg, H. C. Hansson, C. Johansson, H. Areskoug, K. Persson, and B. Jarvholm, “Comparative health impact assessment of local and regional particulate air pollutants in Scandinavia,” Ambio, vol. 34, no. 1, pp. 11–19, 2005.
[18]  U. C. Kulshrestha, A. Saxena, N. Kumar, K. M. Kumari, and S. S. Srivastava, “Seasonal variability of particulate matter and its ionic components at Agra,” Indian Journal of Environmental Protection, vol. 13, pp. 30–33, 1992.
[19]  A. K. Gupta, K. Karar, and A. Srivastava, “Chemical mass balance source apportionment of PM10 and TSP in residential and industrial sites of an urban region of Kolkata, India,” Journal of Hazardous Materials, vol. 142, no. 1-2, pp. 279–287, 2007.
[20]  WHO, Health Risks of Heavy Metals from Long-Range Trans Boundary Air Pollution, 2007.
[21]  A. Kulshrestha, P. G. Satsangi, J. Masih, and A. Taneja, “Metal concentration of PM2.5 and PM10 particles and seasonal variations in urban and rural environment of Agra, India,” Science of the Total Environment, vol. 407, no. 24, pp. 6196–6204, 2009.
[22]  R. M. Tripathi, A. V. Kumar, S. T. Manikandan, S. Bhalke, T. N. Mahadevan, and V. D. Puranik, “Vertical distribution of atmospheric trace metals and their sources at Mumbai, India,” Atmospheric Environment, vol. 38, no. 1, pp. 135–146, 2004.
[23]  C. Vijayanand, P. Rajaguru, K. Kalaiselvi, K. P. Selvam, and M. Palanivel, “Assessment of heavy metal contents in the ambient air of the Coimbatore city, Tamilnadu, India,” Journal of Hazardous Materials, vol. 160, no. 2-3, pp. 548–553, 2008.
[24]  V. Shridhar, P. S. Khillare, T. Agarwal, and S. Ray, “Metallic species in ambient particulate matter at rural and urban location of Delhi,” Journal of Hazardous Materials, vol. 175, no. 1–3, pp. 600–607, 2010.
[25]  E. von Schneidemesser, E. A. Stone, T. A. Quraishi, M. M. Shafer, and J. J. Schauer, “Toxic metals in the atmosphere in Lahore, Pakistan,” Science of the Total Environment, vol. 408, no. 7, pp. 1640–1648, 2010.
[26]  B. Ghauri, A. Lodhi, and M. Mansha, “Development of baseline (air quality) data in Pakistan,” Environmental Monitoring and Assessment, vol. 127, no. 1–3, pp. 237–252, 2007.
[27]  M. F. Khan, K. Hirano, and S. Masunaga, “Quantifying the sources of hazardous elements of suspended particulate matter aerosol collected in Yokohama, Japan,” Atmospheric Environment, vol. 44, no. 21-22, pp. 2646–2657, 2010.
[28]  W. Hu and G. P. Wu, “The lead pollution level in particulate of the four cities in China,” Environmental Monitoring in China, vol. 15, pp. 5–7, 1999.
[29]  M. Sohrabpour, H. Mirzaee, S. Rostami, and M. Athari, “Elemental concentration of the suspended particulate matter in the air of Tehran,” Environment International, vol. 25, pp. 75–81, 1999.
[30]  V. K. Mishra, K.-H. Kim, C.-H. Kang, and K. C. Choi, “Wintertime sources and distribution of airborne lead in Korea,” Atmospheric Environment, vol. 38, no. 17, pp. 2653–2664, 2004.
[31]  C. Theodosi, U. Im, A. Bougiatioti, P. Zarmpas, O. Yenigun, and N. Mihalopoulos, “Aerosol chemical composition over Istanbul,” Science of the Total Environment, vol. 408, no. 12, pp. 2482–2491, 2010.
[32]  D. Contini, A. Genga, D. Cesari et al., “Characterisation and source apportionment of PM10 in an urban background site in Lecce,” Atmospheric Research, vol. 95, no. 1, pp. 40–54, 2010.
[33]  A. Limbeck, M. Handler, C. Puls, J. Zbiral, H. Bauer, and H. Puxbaum, “Impact of mineral components and selected trace metals on ambient PM10 concentrations,” Atmospheric Environment, vol. 43, no. 3, pp. 530–538, 2009.
[34]  A. M. S. de la Campa, J. de la Rosa, X. Querol, A. Alastuey, and E. Mantilla, “Geochemistry and origin of PM10 in the Huelva region, Southwestern Spain,” Environmental Research, vol. 103, no. 3, pp. 305–316, 2007.
[35]  M. R. Heal, L. R. Hibbs, R. M. Agius, and I. J. Beverland, “Total and water-soluble trace metal content of urban background PM10, PM2.5 and black smoke in Edinburgh, UK,” Atmospheric Environment, vol. 39, no. 8, pp. 1417–1430, 2005.
[36]  M. Singh, P. A. Jaques, and C. Sioutas, “Size distribution and diurnal characteristics of particle-bound metals in source and receptor sites of the Los Angeles Basin,” Atmospheric Environment, vol. 36, no. 10, pp. 1675–1689, 2002.
[37]  U. C. Kulshrestha, T. Nageswara Rao, S. Azhaguvel, and M. J. Kulshrestha, “Emissions and accumulation of metals in the atmosphere due to crackers and sparkles during Diwali festival in India,” Atmospheric Environment, vol. 38, no. 27, pp. 4421–4425, 2004.
[38]  R. Vecchi, G. Marcazzan, and G. Valli, “A study on nighttime-daytime PM10 concentration and elemental composition in relation to atmospheric dispersion in the urban area of Milan (Italy),” Atmospheric Environment, vol. 41, no. 10, pp. 2136–2144, 2007.
[39]  E. Furimsky, “Characterization of trace element emissions from coal combustion by equilibrium calculations,” Fuel processing technology, vol. 63, no. 1, pp. 29–44, 2000.
[40]  J. Mohn, R. Figi, P. Graf, et al., “Wood combustion—clean energy?” in Proceedings of the 5th International Conference on Emission Monitoring, Odense, Denmark, September 2002.
[41]  Y. Sun, G. Zhuang, W. Zhang, Y. Wang, and Y. Zhuang, “Characteristics and sources of lead pollution after phasing out leaded gasoline in Beijing,” Atmospheric Environment, vol. 40, no. 16, pp. 2973–2985, 2006.
[42]  P. S. Khillare, S. Balachandran, and B. R. Meena, “Spatial and temporal variation of heavy metals in atmospheric aerosol of Delhi,” Environmental Monitoring and Assessment, vol. 90, no. 1-3, pp. 1–21, 2004.
[43]  Y. Q. Wang, X. Y. Zhang, and R. R. Draxler, “TrajStat: GIS-based software that uses various trajectory statistical analysis methods to identify potential sources from long-term air pollution measurement data,” Environmental Modelling and Software, vol. 24, no. 8, pp. 938–939, 2009.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133