A complex example of electrolytic redox system involving 47 species, 3 electron-active elements and five (3 am-phiprotic + 2 aprotic) co-solvents, is presented. Mixed solvates of the species thus formed are admitted in the system considered. It is proved that the Generalized Electron Balance (GEB) in its simplest form obtained according to the Approach II to GEB is identical with the one obtained for aqueous media and binary-solvent system, and is equivalent to the Approach I to GEB.
Michalowski, T., Toporek, M., Michalowska-Kaczmarczyk, A.M. and Asuero, A.G. (2013) New Trends in Studies on Electrolytic Redox Systems. Electrochimica Acta, 109, 519-531. http://dx.doi.org/10.1016/j.electacta.2013.07.125
[3]
Michalowski, T., Michalowska-Kaczmarczyk, A.M. and Toporek, M. (2013) Formulation of General Criterion Distinguishing between Non-Redox and Redox Systems, Electrochimica Acta, 112, 199-211. http://dx.doi.org/10.1016/j.electacta.2013.08.153
[4]
Michalowska-Kaczmarczyk, A.M. and Michalowski, T. (2013) Comparative Balancing of Non-Redox and Redox Electrolytic Systems and Its Consequences. American Journal of Analytical Chemistry, 4, 46-53. http://dx.doi.org/10.4236/ajac.2013.410A1006
[5]
Michalowska-Kaczmarczyk, A.M. and Michalowski, T. (2014) Compact Formulation of Redox Systems According to GATES/GEB Principles, Journal of Analytical Sciences, Methods and Instrumentation, 4, 39-45. http://dx.doi.org/10.4236/jasmi.2014.42006
[6]
Michalowski, T., Ponikvar-Svet, M., Asuero, A.G. and Kupiec, K. (2012) Thermodynamic and Kinetic Effects Involved with pH Titration of As(III) with Iodine in a Buffered Malonate System. Journal of Solution Chemistry, 41, 436-446. http://dx.doi.org/10.1007/s10953-012-9815-6
[7]
Michalowski, T. (2011) Application of GATES and MATLAB for Resolution of Equilibrium, Metastable and Non-Equilibrium Electrolytic Systems, Chapter 1. In: Michalowski, T., Ed., Applications of MATLAB in Science and Engineering, InTech—Open Access Publisher in the Fields of Science, Technology and Medicine, 1-34. http://www.intechopen.com/books/show/title/applications-of-matlab-in-science-and-engineering
[8]
Michalowska-Kaczmarczyk, A.M., Michalowski, T., Asuero, A.G., Rymanowski, M. and Toporek, M. (2014) Formulation of Titration Curves for Some Redox Systems. American Journal of Analytical Chemistry, 5, 861-878. http://dx.doi.org/10.4236/ajac.2014.513095
[9]
Pilarski, B., Dobkowska, A., Foks, H. and Michalowski, T. (2010) Modeling of Acid-Base Equilibria in Binary-Solvent Systems: A Comparative Study. Talanta, 80, 1073-1080. http://dx.doi.org/10.1016/j.talanta.2009.07.033
[10]
Asuero, A.G., Pilarski, B., Dobkowska, A. and Michalowski, T. (2013) On the Isohydricity Concept—Some Comments, Talanta 112, 49-54. http://dx.doi.org/10.1016/j.talanta.2013.03.067
[11]
Michalowski, T., Pilarski, B., Asuero, A.G. and Michalowska-Kaczmarczyk, A.M. (2014) Modeling of Acid-Base Properties in Binary-Solvent Systems, Chapter 9.4. In: Wypych. G., Ed., Handbook of Solvents, Vol. 1 Properties, ChemTec Publishing, Toronto, 623-648.
