The catalytic efficiency of modified nanodiamonds (MND) in reactions of
interaction between organic compounds was demonstrated on the example of
azocoupling reaction (hydrogen peroxide-4-aminoantipyrine-phenol). It was found
that catalytic action of MND was caused by redox active metal ions of Fe and Cu
located on the MND surface. The neutralization of the ions significantly
decreased catalytic properties of MND.
References
[1]
Chiganova, G.A. (1994) Study of Surface Properties of Ultrafine Diamonds. Colloid Journal, 56, 266-268.
[2]
Mochalin, V.N., Shenderova, O., Ho, D. and Gogotsi, Y. (2012) The Properties and Applications of Nanodiamonds. Nature Nanotechnology, 7, 11-23. http://dx.doi.org/10.1038/nnano.2011.209
[3]
Bogatyreva, G.P., Ishchenko, E.V. and Marinich, M.A. (2000) Catalytic Properties of Pd, Pd-Ag, and Ag Deposited onto Diamond Submicron Powders. Sverkhtverdye Materialy, 2, 72-77.
[4]
Bogatyreva, G.P., Marinich, M.A., Ishchenko, E.V., Gvyazdovskaya, V.L., Bazalii, G.A. and Oleinik, N.A. (2004) Application of Modified Nanodiamonds as Catalysts of Heterogeneous and Electrochemical Catalyses. Physics of the Solid State, 46, 718-721. http://dx.doi.org/10.1134/1.1711462
[5]
Zhang, J., Sheng Su, D., Blume, R., Schlogl, R., Wang, R., Yang, X. and Gajovic, A. (2010) Surface Chemistry and Catalytic Reactivity of a Nanodiamond in the Steam-Free Dehydrogenation of Ethylbenzene. Angewandte Chemie International Edition, 49, 8640-8644. http://dx.doi.org/10.1002/anie.201002869
[6]
Yeremin, A.N., Semashko, T.V. and Mikhailova, R.V. (2006) Co-Oxidation of Phenol and 4-Aminoantipyrine, Catalyzed by Polymers and Co-Polymers of Horse Radish Root and Glucose Oxidase of Penicillium funiculosum 46.1. Applied Microbiology and Biotechnology, 42, 452-461.
[7]
Keppy, N.K., Bain, G. and Allen, M.W. (2009) Enzymatic Colorimetric Methods for the Analysis of Human Serum by UV-Visible Spectroscopy. Thermo Fisher Scientific, Madison.
[8]
Kumar, A., Mishra, R.K. and Roy, S.S. (2004) Studies on Impact of Industrial Pollution on Biochemical and Histological Changes in a Catfish, Mystus vittatus (Bloch). In: Kumar, A., Ed., Industrial Pollution & Management, APH Publishing, New Delhi, 1-43.
[9]
Bondar, V.S. and Puzyr, A.P. (2004) Nanodiamonds for Biological Investigations. Physics of the Solid State, 46, 716-719. http://dx.doi.org/10.1134/1.1711457
[10]
Puzyr, A.P. and Bondar, V.S. (2003) Method of Production of Nanodiamonds of Explosive Synthesis with an Increased Colloidal Stability. RU Patent No. 2252192.
[11]
Gibson, N., Shenderova, O., Luo, T.J.M., Moseenkov, S., Bondar, V., Puzyr, A., Purtov, K., Fitzgerald, Z. and Brenner, D.W. (2009) Colloidal Stability of Modified Nanodiamond Particles. Diamond and Related Materials, 18, 620-626. http://dx.doi.org/10.1016/j.diamond.2008.10.049
[12]
Metzler, D.E. (2003) Biochemistry. The Chemical Reactions of Living Cells. 2nd Edition, Academic Press, Waltham.
