The Generalized Electron Balance (GEB), together with charge balance and
concentration balances, completes the set of equations needed for resolution of
electrolytic redox systems. The general formulae for GEB were obtained
according to Approach II to GEB, i.e.,
on the basis of the equation 2?f(O)? f(H)
obtained from elemental balances: f(H)
for H, and f(O) for O. Equivalency of
the Approach II and the Approach I to GEB was proved for an aqueous solution
and a binary-solvent system. On this basis, a compact form of GEB was derived.
References
[1]
Michalowski, T., Toporek, M., Michalowska-Kaczmarczyk, A.M. and Asuero, A.G. (2013) New Trends in Studies on Electrolytic Redox Systems. Electrochimica Acta, 109, 519-531. http://dx.doi.org/10.1016/j.electacta.2013.07.125
[2]
Michalowski, T., Michalowska-Kaczmarczyk, A.M. and Toporek, M. (2013) Formulation of General Criterion Distinguishing between Non-Redox and Redox Systems, Electrochimica Acta, 112, 199-211. http://dx.doi.org/10.1016/j.electacta.2013.08.153
[3]
Michalowska-Kaczmarczyk, A.M. and Michalowski, T. (2013) Comparative Balancing of Non-Redox and Redox Electrolytic Systems and Its Consequences. American Journal of Analytical Chemistry, 4, 46-53. http://dx.doi.org/10.4236/ajac.2013.410A1006
[4]
Michalowski, T. (2011) Application of GATES and MATLAB for Resolution of Equilibrium, Metastable and Non-Equilibrium Electrolytic Systems, Chapter 1, 1-34. In: Michalowski, T., Ed., Applications of MATLAB in Science and Engineering, InTech. http://www.intechopen.com/books/show/title/applications-of-matlab-in-science-and-engineering.
[5]
Michalowski, T., Pilarski, B., Asuero, A.G. and Michalowska-Kaczmarczyk, A.M. (2014) Modeling of Acid-Base Properties in Binary-Solvent Systems, Chapter 9.4. In: Wypych, G., Ed., Handbook of Solvents (2nd Edition), in print.
[6]
Michalowski, T. (2001) Calculations in Analytical Chemistry with Elements of Computer Programming (in Polish) PK, Cracow. http://suw.biblos.pk.edu.pl/resourceDetails&rId=3974
[7]
Michalowski, T. and Lesiak, A. (1994) Formulation of Generalized Equations for Redox Titration Curves. Chemia Analityczna (Warsaw), 13, 623-637.
[8]
Michalowski, T., Rymanowski, M. and Pietrzyk, A. (2005) Non-Typical Bronsted’s Acids and Bases. Journal of Chemical Education, 82, 470-472. http://dx.doi.org/10.1021/ed082p470
[9]
Mancinelli, R., Sodo, A., Bruni, F., Ricci, M.A. and Soper, A.K. (2009) Influence of Concentration and Anion Size on Hydration of H+ Ions and Water Structure. Journal of Physical Chemistry B, 113, 4075-4080. http://suw.biblos.pk.edu.pl/resourceDetails&rId=3974 http://dx.doi.org/10.1021/jp805220j
[10]
Michalowski, T. (1994) Calculation of pH and Potential E for Bromine Aqueous Solutions. Journal of Chemical Education, 71, 560-562. http://dx.doi.org/10.1021/ed071p560 .
Asuero, A.G. and Michalowski, T. (2011) Comprehensive Formulation of Titration Curves Referred to Complex Acid-Base Systems and Its Analytical Implications. Critical Reviews in Analytical Chemistry, 41, 151-187. http://dx.doi.org/10.1080/10408347.2011.559440
[13]
Michalowski, T. and Asuero, A.G. (2012) New Approaches in Modelling the Carbonate Alkalinity and Total Alkalinity. Critical Reviews in Analytical Chemistry, 42, 220-244. http://dx.doi.org/10.1080/10408347.2012.660067
