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Preparation and Characterization of a New Desulfurizer and Its Performance on Removal of SO2

DOI: 10.4236/gep.2014.22011, PP. 68-76

Keywords: Attapulgite, CaO, Desulfurization, SO2, Adsorption

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Abstract:

Sulfur dioxide is one of the major pollutants resulting from fuel combustion. In this study, CaO and attapulgite were utilized as raw material for synthesizing CaO/attapulgite (CaO/ATP) desulfurizer. The physicochemical characteristics of CaO/ATP desulfurizer were evaluated by various techniques such as XRD, SEM, FT-IR. The performance of samples was studied in dynamic conditions. Major factors affecting on desulfurization such as weight ratio of CaO to total, types of modifiers, roasting time and temperature were investigated. The desulfurization agent synthesized under optimal synthesis conditions with CaO content of 30 wt% and NaOH modifier, and the desulfurization roasting time of 2 hours and roasting temperature of 600°C, exhibit sulfur tolerance of 10.15 wt%. This desulfurizer with excellent absorbency and catalysis of desulfurization, economical and?environment-friendly, could be especially useful in industrial applications.

References

[1]  Aytar, P., Gedikli, S., Sam, M., ünal, A., Çabuk, A., Kolankaya, N., & Yürüm, A. (2011). Desulphurization of Some Low-Rank Turkish Lignites with Crude Laccase Produced from Trametes Versicolor ATCC 200801. Fuel Processing Technology, 92, 71-76. http://dx.doi.org/10.1016/j.fuproc.2010.08.022
[2]  Cao, E., Bryant, R., & Williams, D. J. A. (1996). Electrochemical Properties of Na-Attapulgite. Journal of Colloid and Interface Science, 179, 143-150. http://dx.doi.org/10.1006/jcis.1996.0196
[3]  Chen, B., & Zhang, X. X. (2003). The Research Development of the Numerical Model of Single-Particle Dry Method Desulfurization. Industrial Boiler, 77, 16-19.
[4]  Chen, B., Jin, H., & Zhang, X. X. (2003). Original Uneven Porosity Desulphurization Model Research of Small Particle. Journal of Lanzhou University, 39, 41-43.
[5]  Chen, B., Jin, H., & Zhang, X. X. (2004). A Mathematic Model of Non-Homogenous Original Porosity for Dry method Desulfurization. Environmental Pollution Prevention, 26, 46-47.
[6]  Frost, R. L., Cash, G. A., Kloprogge, J. T. et al. (1998). Rocky Mountain Leather’, Sepiolite Andattapulgite—An Infrared Emission Spectroscopic Study. Vibrational Spectroscopy, 16, 173-184. http://dx.doi.org/10.1016/S0924-2031(98)00014-9
[7]  Görkem, B., & Oğuz, H. (2006). Development of an Active Sorbent from Fly Ash for Dry Desulphurization of Simulated Flue Gas in a Fluidized-Bed Reactor. Chemical Engineering Journal, 119, 147-152. http://dx.doi.org/10.1016/j.cej.2006.03.018
[8]  Hernández-Maldonado, A. J., Qi, G. S., & Yang, R. T. (2005). Desulfurization of Commercial Fuels by π-Complexation: Monolayer CuCl/γ-Al2O3. Applied Catalysis B: Environmental, 61, 236-242. http://dx.doi.org/10.1016/j.apcatb.2005.05.012
[9]  Li, A., Zhang, J. P., & Wang, A. Q. (2007). Utilization of Starch and Clay for the Preparation of Superabsorbent Composite. J. Bior. Tech., 98, 327-332. http://dx.doi.org/10.1016/j.biortech.2005.12.026
[10]  Li, J. J., Kobayashi, N., & Hu, Y. Q. (2008). The Activated Coke Preparation for SO2 Adsorption by Using Flue Gas from Coal Power Plant. Chemical Engineering and Processing, 47, 118-127. http://dx.doi.org/10.1016/j.cep.2007.08.001
[11]  Lin, Y. S., & Deng, S. G. (1998). Removal of Trace Sulfur Dioxide from Gas Stream by Regenerative Sorption Processes. Separation and Purification Technology, 13, 65-77. http://dx.doi.org/10.1016/S1383-5866(97)00062-2
[12]  Liu, B. S., Wei, X. N., Zhan, Y. P., Chang, R. Z., Subhan, F., & Au, C. T. (2011). Preparation and Desulfurization Performance of LaMeOx/SBA-15 for Hot Coal Gas. Applied Catalysis B: Environmental, 102, 27-36. http://dx.doi.org/10.1016/j.apcatb.2010.11.020
[13]  Ma, J. R., Liu, Z. Y., Liu, S. J., & Zhu, Z. P. (2003). A Regenerable Fe/AC Desulfurizer for SO2 Adsorption at Low Temperatures. Applied Catalysis B: Environmental, 45, 301-309. http://dx.doi.org/10.1016/S0926-3373(03)00176-0
[14]  Pan, Y. G., Perales, J. F., Velo, E., &Puigjaner, L. (2005). Kinetic Behaviour of Iron Oxide Sorbent in Hot Gas Desulfurization. Fuel, 84, 1105-1109. http://dx.doi.org/10.1016/j.fuel.2004.11.025
[15]  Perderiset, M., Baillif, P., & Jaurand, M. C. (1988). Chemical Analysis and Photoelectron Spectroscopy of the Adsorption of Macromolecules on the Surface of Attapulgite. Journal of Colloid and Interface Science, 121, 381-391. http://dx.doi.org/10.1016/0021-9797(88)90441-9
[16]  Shen, Y. F., Sun, T. H., & Jia, J. P. (2012). A Novel Desulphurization Process of Coal Water Slurry via Sodium Metaborate Electroreduction in the Alkaline System. Fuel, 96, 250-256. http://dx.doi.org/10.1016/j.fuel.2012.01.003
[17]  Wang, L., & Sheng, J. (2005). Preparation and Properties of Polypropylene/Org-Attapulgite Nanocomposites. Polymer Journal, 46, 6243-6249. http://dx.doi.org/10.1016/j.polymer.2005.05.067
[18]  Wang, Y. P., Liu, Y., Dong, Y. H., & Ma, Y. J. (2011). Adsorption of Ammonia Nitrogen on Modified Palygorskites an d Zeolite in Waste Water. Applied Chemical Industry, 40, 985-992.
[19]  Wieckowska, J. (1995). Catalytic and Adsorptive Desulphurization of Gases. Catalysis Today, 24, 405-465. http://dx.doi.org/10.1016/0920-5861(95)00021-7
[20]  Yan, Y., Peng, X. F., Jia, L. et al. (2002) Study on the Distributed Pore characteristic of Dry Flue Gas Desulfurization. Energy environment, 20, 38-41.
[21]  Zhang, J., Chen, H., & Wang, A. (2005). Study on Superabsorbent Composite. III. Swelling Behaviors of Polyacrylamide/ Attapulgite Composite Based on Acidified Attapulgite and Organo-Attapulgite. European Polymer Journal, 41, 2434- 2442. http://dx.doi.org/10.1016/j.eurpolymj.2005.03.022

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