Acrylic resin (AR) based electromagnetic interference (EMI) shielding composites have been prepared by incorporation of up to 30?wt% activated charcoal (AC) in AR matrix. These composites have been characterized by XRD, Raman spectroscopy, scanning electron microscopy, dielectric, and EMI shielding measurement techniques. XRD patterns and Raman studies confirm the incorporation of AC particles inside AR matrix and suggest possible interactions between phases. The SEM images show that incorporation of AC particles leads to systematic change in the morphology of composites especially the formation of porous structure. The dielectric measurements show that 30?wt% AC loading composite display higher relative permittivity value (~79) compared to pristine AR (~5). Further, the porous structure, electrical conductivity, and permittivity value contribute towards EMI shielding effectiveness value of ?36?dB (attenuation of >99.9% of incident radiation) for these composites, thereby demonstrating their suitability for making efficient EMI shielding coatings. 1. Introduction Electromagnetic (EM) interference (EMI) is an offshoot of explosive growth of electronics and telecommunication in the modern society [1–3]. The EMI among electronic instruments/appliances may lead to degradation of device performance and may even adversely affect human health [4, 5]. Due to possible hazards of EMI only, the use of EM wave receipting/emitting electronic gadgets is prohibited inside sensitive zones, for example, during flight or inside hospital’s ICUs [1, 5, 6]. Therefore, systematic strategies and suitable counter measures are essential to prevent/suppress EMI so as to ensure uninterrupted performance of appliances [1–9]. The primary mechanism of shielding is based on reflection and the material used for shielding by reflection requires mobile charge carriers; that is, shield should have conducting property [9, 10]. Consequently, metals (in the form of filler, coatings, or laminates) are the most common shielding material which uses primarily reflection mechanism for shielding along with minor absorption component. However, metals suffer from problems like poor wear/scratch resistance, corrosion susceptibility, high density, difficult processing, and high cost [1, 6, 9]. The secondary shielding mechanism is absorption for which shield material should have electrical or magnetic dipoles [9–12] along-with finite electrical conductivity. For such purpose materials with high dielectric constant like ZnO, SiO2, TiO2, BaTiO3, or high magnetic permeability, for example, carbonyl iron,
References
[1]
P. Saini and M. Arora, “Microwave absorption and EMI shielding behavior of nanocomposites based on intrinsically conducting polymers, graphene and carbon nanotubes,” in New Polymers for Special Applications, A. De Souza Gomes, Ed.A. De Souza Gomes, Ed., InTech, 2012.
[2]
H. W. Ott, Electromagnetic Compatibility Engineering, John Wiley & Sons, Hoboken, NJ, USA, 2009.
[3]
P. Saini, “Electrical properties and electromagnetic interference shielding response of electrically conducting thermosetting nanocomposites,” in Thermoset Nanocomposites, V. Mittal, Ed., Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2013.
[4]
L. Olmedo, P. Hourquebie, and F. Jousse, Handbook of Organic Conductive Molecules and Polymers, vol. 2, John Wiley & Sons, Chichester, UK, 1997.
[5]
P. Saini, M. Arora, G. Gupta, B. K. Gupta, V. N. Singh, and V. Choudhary, “High permittivity polyaniline-barium titanate nanocomposites with excellent electro-magnetic interference shielding response,” Nanoscale, vol. 5, pp. 4330–4336, 2013.
[6]
P. Saini, V. Choudhary, B. P. Singh, R. B. Mathur, and S. K. Dhawan, “Enhanced microwave absorption behavior of polyaniline-CNT/polystyrene blend in 12.4-18.0 GHz range,” Synthetic Metals, vol. 161, no. 15-16, pp. 1522–1526, 2011.
[7]
Y. Yang, M. C. Gupta, K. L. Dudley, and R. W. Lawrence, “Conductive carbon nanofiber-polymer foam structures,” Advanced Materials, vol. 17, no. 16, pp. 1999–2003, 2005.
[8]
N. F. Colaneri and L. W. Shacklette, “EMI shielding measurements of conductive polymer blends,” IEEE Transactions on Instrumentation and Measurement, vol. 41, no. 2, pp. 291–297, 1992.
[9]
P. Saini, V. Choudhary, B. P. Singh, R. B. Mathur, and S. K. Dhawan, “Polyaniline-MWCNT nanocomposites for microwave absorption and EMI shielding,” Materials Chemistry and Physics, vol. 113, no. 2-3, pp. 919–926, 2009.
[10]
D. D. L. Chung, “Electromagnetic interference shielding effectiveness of carbon materials,” Carbon, vol. 39, no. 2, pp. 279–285, 2001.
[11]
S. M. Abbas, A. K. Dixit, R. Chatterjee, and T. C. Goel, “Complex permittivity and microwave absorption properties of BaTiO3-polyaniline composite,” Materials Science and Engineering B, vol. 123, no. 2, pp. 167–171, 2005.
[12]
D. D. L. Chung, “Materials for electromagnetic interference shielding,” Journal of Materials Engineering and Performance, vol. 9, no. 3, pp. 350–354, 2000.
[13]
P. Saini, V. Choudhary, N. Vijayan, and R. K. Kotnala, “Improved electromagnetic interference shielding response of poly (aniline)-coated fabrics containing dielectric and magnetic nanoparticles,” Journal of Physical Chemistry C, vol. 116, pp. 13403–13412, 2012.
[14]
P. Singh, V. K. Babbar, A. Razdan, S. L. Srivastava, and R. K. Puri, “Complex permeability and permittivity, and microwave absorption studies of Ca(CoTi)xFe12-2xO19 hexaferrite composites in X-band microwave frequencies,” Materials Science and Engineering B, vol. 67, no. 3, pp. 132–138, 1999.
[15]
N. Li, Y. Huang, F. Du et al., “Electromagnetic Interference (EMI) shielding of single-walled carbon nanotube epoxy composites,” Nano Letters, vol. 6, no. 6, pp. 1141–1145, 2006.
[16]
P. Saini and V. Choudhary, “Enhanced electromagnetic interference shielding effectiveness of polyaniline functionalized carbon nanotubes filled polystyrene,” Journal of Nanoparticle Research, vol. 15, article 1415, 7 pages, 2013.
[17]
S. N. Tripathi, P. Saini, D. Gupta, and V. Choudhary, “Electrical and mechanical properties of PMMA/reduced graphene oxide nanocomposites prepared via in situ polymerization,” Journal of Material Science, vol. 48, pp. 6223–6232, 2013.
[18]
P. Saini, V. Choudhary, K. N. Sood, and S. K. Dhawan, “Electromagnetic interference shielding behavior of polyaniline/graphite composites prepared by in situ emulsion pathway,” Journal of Applied Polymer Science, vol. 113, no. 5, pp. 3146–3155, 2009.
[19]
J. Wu and D. D. L. Chung, “Increasing the electromagnetic interference shielding effectiveness of carbon fiber polymer-matrix composite by using activated carbon fibers,” Carbon, vol. 40, no. 3, pp. 445–447, 2002.
[20]
E. Varrla, S. Venkataraman, and R. Sundara, “Functionalized graphene-PVDF foam composites for EMI shielding,” Macromolecular Materials and Engineering, vol. 296, no. 10, pp. 894–898, 2011.
[21]
Y. Yang, M. C. Gupta, K. L. Dudley, and R. W. Lawrence, “Novel carbon nanotube—polystyrene foam composites for electromagnetic interference shielding,” Nano Letters, vol. 5, no. 11, pp. 2131–2134, 2005.
[22]
P. K. Vallittu, “Flexural properties of acrylic resin polymers reinforced with unidirectional and woven glass fibers,” The Journal of Prosthetic Dentistry, vol. 81, no. 3, pp. 318–326, 1999.
[23]
H.-S. Park, I.-M. Yang, J.-P. Wu et al., “Synthesis of silicone-acrylic resins and their applications to superweatherable coatings,” Journal of Applied Polymer Science, vol. 81, no. 7, pp. 1614–1623, 2001.
[24]
S. D. Khan, M. Arora, C. Puri, M. A. Wahab, and P. Saini, “Synthesis and characterization of acrylic resin/activated carbon composites,” Indian Journal of Pure and Applied Physics, vol. 52, no. 4, pp. 251–254, 2014.
[25]
L. Olmedo, P. Hourquebie, and F. Jousse, “Microwave properties of conductive polymers,” Synthetic Metals, vol. 69, no. 1-3, pp. 205–208, 1995.
[26]
C. K. Das and A. Mandal, “Microwave absorbing properties of DBSA-doped polyaniline/BaTiO3-Ni0.5Zn0.5Fe2O4,” Journal of Materials Science Research, vol. 1, no. 1, pp. 45–53, 2012.
[27]
P. Saini and V. Choudhary, “Electrostatic charge dissipation and electro-magnetic interference shielding response of polyaniline based conducting fabrics,” Indian Journal of Pure and Applied Physics, vol. 51, pp. 112–117, 2013.
[28]
R. Kumar, S. R. Dhakate, P. Saini, and R. B. Mathur, “Improved electromagnetic interference shielding effectiveness of light weight carbon foam by ferrocene accumulation,” RSC Advances, vol. 3, no. 13, pp. 4145–4151, 2013.
[29]
P. Saini and M. Arora, “Formation mechanism, electronic properties and microwave shielding by nano-structured polyanilines prepared by template free route using surfactant dopants,” Journal of Materials Chemistry A, vol. 1, no. 31, pp. 8926–8934, 2013.
[30]
J. Joo and A. J. Epstein, “Electromagnetic radiation shielding by intrinsically conducting polymers,” Applied Physics Letters, vol. 65, no. 18, pp. 2278–2280, 1994.
[31]
L. W. Shacklette, N. F. Colaneri, V. G. Kulkarni, and B. Wessling, “EMI Shielding of intrinsically conductive polymers,” Journal of Vinyl and Additive Technology, vol. 14, no. 2, pp. 118–122, 1992.
[32]
P. Saini, V. Choudhary, and S. K. Dhawan, “Electrical properties and EMI shielding behavior of highly thermally stable polyaniline/colloidal graphite composites,” Polymers for Advanced Technologies, vol. 20, no. 4, pp. 355–361, 2009.
[33]
P. Saini and V. Choudhary, “Structural details, electrical properties, and electromagnetic interference shielding response of processable copolymers of aniline,” Journal of Materials Science, vol. 48, no. 2, pp. 797–804, 2013.
[34]
Y. K. Hong, C. Y. Lee, C. K. Jeong, D. E. Lee, K. Kim, and J. Joo, “Method and apparatus to measure electromagnetic interference shielding efficiency and its shielding characteristics in broadband frequency ranges,” Review of Scientific Instruments, vol. 74, no. 2, pp. 1098–1102, 2003.
[35]
H.-B. Zhang, Q. Yan, W.-G. Zheng, Z. He, and Z.-Z. Yu, “Tough graphene-polymer microcellular foams for electromagnetic interference shielding,” ACS Applied Materials and Interfaces, vol. 3, no. 3, pp. 918–924, 2011.
[36]
Y. Yang, M. C. Gupta, K. L. Dudley, and R. W. Lawrence, “A comparative study of EMI shielding properties of carbon nanofiber and multi-walled carbon nanotube filled polymer composites,” Journal of Nanoscience and Nanotechnology, vol. 5, no. 6, pp. 927–931, 2005.
[37]
D.-X. Yan, H. Pang, L. Xu et al., “Electromagnetic interference shielding of segregated polymer composite with an ultralow loading of in situ thermally reduced graphene oxide,” Nanotechnology, vol. 25, no. 14, Article ID 145705, 2014.