Challenges associated with damage tolerance in polymer matrix composites must be successfully addressed in order to ensure highly reliable structures with significant weight savings. Self-healing materials provide a viable means to surmount damage tolerance concerns, thereby allowing for the realization of the mass reduction such structures have promised but not yet achieved. Introduction of multifunctional properties into self-healing composites can further extend their usefulness. This study examines the incorporation of carbon nanotubes into a self-healing composite in order to achieve this. Composite panels were fabricated with carbon fibers, a bismaleimide tetrafuran (2MEP4F) polymer resin, and various carbon nanotube materials. The composites exhibit enhancement in electrical, mechanical, and thermal properties. The healing mechanism is a thermally activated reversible polymerization of the 2MEP4F resin. The proposed method of heating exploits the enhanced microwave absorption inherent to carbon nanotubes to provide the thermal energy required for the reversible polymerization. Microwave testing demonstrated that the heating efficiency is increased, allowing uniform heating to the required temperature for polymer healing. Impacted composites show localized heating at the damage site, which implies that microwave heating can also be used as a means for damage detection and potential structural health monitoring. 1. Introduction The National Aeronautics and Space Administration (NASA) is currently evaluating composite materials for primary and secondary structures in habitat modules, crew vehicles, pressure vessels, and other potential applications. Lighter-weight materials with high specific strength can lead to drastic reductions in uptake mass, resulting in more cost effective space exploration. Such materials can have similar benefits in commercial applications such as aircrafts, vehicles, and wind turbine blades, as well as a variety of infrastructural applications. As such they are of great interest not only to NASA but also to the commercial sector. Polymer matrix composites have attracted much attention due to their relatively high strength, light weight, and low cost. An integral design concern, however, is that of damage tolerance. Nearly imperceptible cracks may form upon impact which, while being microscopic, may have drastic effects on structural integrity. As a result, structural composites are designed to be thicker and heavier than would otherwise be required, thus negating some of the weight savings they promise. One way to
References
[1]
D. Y. Wu, S. Meure, and D. Solomon, “Self-healing polymeric materials: a review of recent developments,” Progress in Polymer Science, vol. 33, no. 5, pp. 479–522, 2008.
[2]
S. D. Bergman and F. Wudl, “Mendable polymers,” Journal of Materials Chemistry, vol. 18, no. 1, pp. 41–62, 2008.
[3]
M. R. Kessler, “Self-healing: a new paradigm in materials design,” Proceedings of the Institution of Mechanical Engineers G: Journal of Aerospace Engineering, vol. 221, no. 4, pp. 479–495, 2007.
[4]
J. W. C. Pang and I. P. Bond, “A hollow fibre reinforced polymer composite encompassing self-healing and enhanced damage visibility,” Composites Science and Technology, vol. 65, no. 11-12, pp. 1791–1799, 2005.
[5]
B. J. Blaiszik, M. M. Caruso, D. A. McIlroy, J. S. Moore, S. R. White, and N. R. Sottos, “Microcapsules filled with reactive solutions for self-healing materials,” Polymer, vol. 50, no. 4, pp. 990–997, 2009.
[6]
J. Hu, H.-Q. Chen, and Z. Zhang, “Mechanical properties of melamine formaldehyde microcapsules for self-healing materials,” Materials Chemistry and Physics, vol. 118, no. 1, pp. 63–70, 2009.
[7]
T. F. Scott, A. D. Schneider, W. D. Cook, and C. N. Bowman, “Photoinduced plasticity in cross-linked polymers,” Science, vol. 308, no. 5728, pp. 1615–1617, 2005.
[8]
Y. Amamoto, J. Kamada, H. Otsuka, A. Takahara, and K. Matyjaszewski, “Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units,” Angewandte Chemie, vol. 50, no. 7, pp. 1660–1663, 2011.
[9]
M. E. Garcia, Y. Lin, and H. A. Sodano, “Autonomous materials with controlled toughening and healing,” Journal of Applied Physics, vol. 108, no. 9, Article ID 093512, 2010.
[10]
F. Ghezzo, D. R. Smith, T. N. Starr et al., “Development and characterization of healable carbon fiber composites with a reversibly cross linked polymer,” Journal of Composite Materials, vol. 44, no. 13, pp. 1587–1603, 2010.
[11]
X. Chen, F. Wudl, A. K. Mal, H. Shen, and S. R. Nutt, “New thermally remendable highly cross-linked polymeric materials,” Macromolecules, vol. 36, no. 6, pp. 1802–1807, 2003.
[12]
T. A. Plaisted and S. Nemat-Nasser, “Quantitative evaluation of fracture, healing and re-healing of a reversibly cross-linked polymer,” Acta Materialia, vol. 55, no. 17, pp. 5684–5696, 2007.
[13]
M. L. Szalai, D. V. McGrath, D. R. Wheeler, T. Zifer, and J. R. McElhanon, “Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts,” Macromolecules, vol. 40, no. 4, pp. 818–823, 2007.
[14]
J. S. Park, T. Darlington, A. F. Starr, K. Takahashi, J. Riendeau, and H. Thomas Hahn, “Multiple healing effect of thermally activated self-healing composites based on Diels-Alder reaction,” Composites Science and Technology, vol. 70, no. 15, pp. 2154–2159, 2010.
[15]
J. C. J. Bart, Additives in Polymers: Industrial Analysis and Applications, John Wiley & Sons, New York, NY, USA, 2005.
[16]
T. J. Imholt, C. A. Dyke, B. Hasslacher et al., “Nanotubes in microwave fields: light emission, intense heat, outgassing and reconstruction,” Chemistry of Materials, vol. 15, no. 21, pp. 3969–3970, 2003.
[17]
P. Zhihua, P. Jingcui, P. Yanfeng, O. Yangyu, and N. Yantao, “Investigation of the microwave absorbing mechanisms of HiPco carbon nanotubes,” Physica E, vol. 40, no. 7, pp. 2400–2405, 2008.
[18]
K. R. Paton and A. H. Windle, “Efficient microwave energy absorption by carbon nanotubes,” Carbon, vol. 46, no. 14, pp. 1935–1941, 2008.
[19]
J. A. Menéndez, A. Arenillas, B. Fidalgo et al., “Microwave heating processes involving carbon materials,” Fuel Processing Technology, vol. 91, no. 1, pp. 1–8, 2010.
[20]
A. L. Higginbotham, P. G. Moloney, M. C. Waid et al., “Carbon nanotube composite curing through absorption of microwave radiation,” Composites Science and Technology, vol. 68, no. 15-16, pp. 3087–3092, 2008.
[21]
R. G. de Villoria, N. Yamamoto, A. Miravete, and B. L. Wardle, “Multi-physics damage sensing in nano-engineered structural composites,” Nanotechnology, vol. 22, no. 18, Article ID 185502, 2011.
[22]
R. G. de Villoria, N. Yamamoto, A. Miravete, and B. L. Wardle, “Purification and characterization of single-wall carbon nanotubes,” Journal of Physical Chemistry B, vol. 105, no. 6, pp. 1157–1161, 2001.
[23]
P. Nikolaev, O. Gorelik, R. K. Allada, E. Sosa, S. Arepalli, and L. Yowell, “Soft-bake purification of single-walled carbon nanotubes produced by pulsed laser vaporization,” Journal of Physical Chemistry C, vol. 111, no. 48, pp. 17678–17683, 2007.
[24]
L. Yowell, P. Nikolaev, O. Gorelik, R. K. Allada, E. Sosa, and S. Arepalli, “Soft-Bake purification of SWCNTs produced by pulsed laser vaporization,” NASA TechBriefs, 2013.
[25]
T. Sterzyński, J. Tomaszewska, K. Piszczek, and K. Skórczewska, “The influence of carbon nanotubes on the PVC glass transition temperature,” Composites Science and Technology, vol. 70, no. 6, pp. 966–969, 2010.
[26]
M. Farbod and S. Khajehpour Tadavani, “Electrical properties and glass transition temperature of multiwalled carbon nanotube/polyaniline composites,” Journal of Non-Crystalline Solids, vol. 358, no. 11, pp. 1339–1344, 2012.
[27]
A. Warrier, A. Godara, O. Rochez et al., “The effect of adding carbon nanotubes to glass/epoxy composites in the fibre sizing and/or the matrix,” Composites A: Applied Science and Manufacturing, vol. 41, no. 4, pp. 532–538, 2010.
[28]
F. Y. Castillo, R. Socher, B. Krause et al., “Electrical, mechanical, and glass transition behavior of polycarbonate-based nanocomposites with different multi-walled carbon nanotubes,” Polymer, vol. 52, no. 17, pp. 3835–3845, 2011.
[29]
X. Yan, Z. Gong, J. Gong, S. Gao, B. Wang, and X. Ruan, “Investigation of the glass transition and viscoelastic properties of polycarbonate/multi-walled carbon nanotube composites by positron annihilation lifetime spectroscopy,” Polymer, vol. 54, no. 2, pp. 798–804, 2013.
[30]
X. Wang, H. Liu, and L. Qiu, “Cationic polymerization of tetrahydrofuran from multiple-walled carbon nanotubes: preparation and glass transition kinetics,” Materials Letters, vol. 61, no. 11-12, pp. 2350–2353, 2007.
[31]
C. Chang and Y. Liu, “Functionalization of multi-walled carbon nanotubes with furan and maleimide compounds through Diels-Alder cycloaddition,” Carbon, vol. 47, no. 13, pp. 3041–3049, 2009.
[32]
M. T. Beck, J. Szépv?lgyi, P. Szabó, and E. Jakab, “Heterogeneous DielsAlder reaction between cyclopentadiene and different solid carbons,” Carbon, vol. 39, pp. 137–158, 2001.
[33]
E. H. Fort and L. T. Scott, “Gas-phase Diels-Alder cycloaddition of benzyne to an aromatic hydrocarbon bay region: groundwork for the selective solvent-free growth of armchair carbon nanotubes,” Tetrahedron Letters, vol. 52, no. 17, pp. 2051–2053, 2011.
[34]
J. Che, T. ?a?in, and W. A. Goddard III, “Thermal conductivity of carbon nanotubes,” Nanotechnology, vol. 11, no. 2, pp. 65–69, 2000.
[35]
J. Hone, M. C. Llaguno, N. M. Nemes et al., “Electrical and thermal transport properties of magnetically aligned single wall carbon nanotube films,” Applied Physics Letters, vol. 77, no. 5, pp. 666–668, 2000.
[36]
J. Hone, M. Whitney, C. Piskoti, and A. Zettl, “Thermal conductivity of single-walled carbon nanotubes,” Physical Review B, vol. 59, no. 4, pp. R2514–R2516, 1999.
[37]
W. Zhang, Z. Zhu, F. Wang, T. Wang, L. Sun, and Z. Wang, “Chirality dependence of the thermal conductivity of carbon nanotubes,” Nanotechnology, vol. 15, no. 8, pp. 936–939, 2004.
[38]
P. Kim, L. Shi, A. Majumdar, and P. L. McEuen, “Thermal transport measurements of individual multiwalled nanotubes,” Physical Review Letters, vol. 87, no. 21, Article ID 215502, 2001.