全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Adsorption Studies of Coconut Shell Carbons Prepared by KOH Activation for Removal of Lead(II) From Aqueous Solutions

DOI: 10.3390/su6010086

Keywords: coconut shell carbons, removal, porous, isotherm, kinetics

Full-Text   Cite this paper   Add to My Lib

Abstract:

Removal of Pb 2+ from aqueous solutions using coconut shell carbons produced by KOH activation is performed in this paper. Morphology and pore structure characteristic of coconut shell carbons are analyzed by SEM and nitrogen adsorption techniques. Effects of adsorbent concentration, agitation time and initial ion concentration on the adsorption behavior are investigated, and adsorption isotherm and kinetics on coconut shell carbons are also studied. The results show that high weight ratio of KOH/sample is favorable to produce rich porous structure. The resultant coconut shell carbons with a high specific surface area of 1135 m 2/g is obtained and demonstrates good adsorption potential on removal of Pb 2+ from aqueous solutions. Adsorption data fit well with Freundlich and Halsey isotherms. The kinetic studies indicate that adsorption behavior can be described by pseudo-second-order kinetic model, which also follows external diffusion and intra-particle diffusion in the adsorption process.

References

[1]  Bahadir, T.; Bakan, G.; Altas, L.; Buyukgungor, H. The investigation of lead removal by biosorption: An application at storage battery industry wastewaters. Enzyme Microb. Technol. 2007, 41, 98–102, doi:10.1016/j.enzmictec.2006.12.007.
[2]  Wang, S.; Gong, W.; Liu, X.; Yao, Y.; Gao, B.; Yue, Q. Removal of lead(II) from aqueous solution by adsorption onto manganese oxide-coated carbon nanotubes. Sep. Purif. Technol. 2007, 58, 17–23, doi:10.1016/j.seppur.2007.07.006.
[3]  Gupta, V.K.; Agarwal, S.; Saleh, T.A. Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. J. Hazard. Mater. 2011, 185, 17–23, doi:10.1016/j.jhazmat.2010.08.053.
[4]  Li, Y.; Wang, S.; Wei, J.; Zhang, X.; Xu, C.; Luan, Z.; Wu, D.; Wei, B. Lead adsorption on carbon nanotubes. Chem. Phys. Lett. 2002, 357, 263–266, doi:10.1016/S0009-2614(02)00502-X.
[5]  Sekar, M.; Sakthi, V.; Rengaraj, S. Kinetics and equilibrium adsorption study of lead(II) onto activated carbon prepared from coconut shell. J. Colloid Interf. Sci. 2004, 279, 307–313, doi:10.1016/j.jcis.2004.06.042.
[6]  O’Connell, D.W.; Birkinshaw, C.; O’Dwyer, T.F. Heavy metal adsorbents prepared from the modification of cellulose: A review. Bioresour. Technol. 2008, 99, 6709–6724, doi:10.1016/j.biortech.2008.01.036.
[7]  Acharya, J.; Sahu, J.N.; Mohanty, C.R.; Meikap, B.C. Removal of lead(II) from wastewater by activated carbon developed from Tamarind wood by zinc chloride activation. Chem. Eng. J. 2009, 149, 249–262, doi:10.1016/j.cej.2008.10.029.
[8]  Ricordel, S.; Taha, S.; Cisse, I.; Dorange, G. Heavy metals removal by adsorption onto peanut husks carbon: Characterization, kinetic study and modeling. Sep. Purif. Technol. 2001, 24, 389–401, doi:10.1016/S1383-5866(01)00139-3.
[9]  Saeed, A.; Iqbal, M.; Akhtar, M.W. Removal and recovery of lead(II) from single and multimetal (Cd, Cu, Ni, Zn) solutions by crop milling waste (black gram husk). J. Hazard. Mater. 2005, 117, 65–73, doi:10.1016/j.jhazmat.2004.09.008.
[10]  Doyurum, S.; Celik, A. Pb(II) and Cd(II) removal fromaqueous solutions by olive cake. J. Hazard. Mater. 2006, 138, 22–28, doi:10.1016/j.jhazmat.2006.03.071.
[11]  Goel, J.; Kadirvelu, K.; Rajagopal, C.; Garg, V.K. Removal of lead(II) by adsorption using treated granular activated carbon: Batch and column studies. J. Hazard. Mater. 2005, 125, 211–220, doi:10.1016/j.jhazmat.2005.05.032.
[12]  Cazetta, A.L.; Vargas, A.M.M.; Nogami, E.M.; Kunita, M.H.; Guilherme, M.R.; Martins, A.C.; Silva, T.L.; Moraes, J.C.G.; Almeida, V.C. NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption. Chem. Eng. J. 2011, 174, 117–125, doi:10.1016/j.cej.2011.08.058.
[13]  Rao, M.M.; Rao, G.P.C.; Seshaiah, K.; Choudary, N.V.; Wang, M.C. Activated carbon from Ceiba pentandra hulls, an agricultural waste, as an adsorbent in the removal of lead and zinc from aqueous solutions. Waste Manag. 2008, 28, 849–858, doi:10.1016/j.wasman.2007.01.017.
[14]  Li, W.; Yang, K.; Peng, J.; Zhang, L.; Guo, S.; Xia, H. Effects of carbonization temperatures on characteristics of porosity in coconut shell chars and activated carbons derived from carbonized coconut shell chars. Ind. Crop. Prod. 2008, 28, 190–198, doi:10.1016/j.indcrop.2008.02.012.
[15]  Bansode, R.R.; Losso, J.N.; Marshall, W.E.; Rao, R.M.; Portier, R.J. Adsorption of metal ions by pecan shell-based granular activated carbons. Bioresour. Technol. 2003, 89, 115–119, doi:10.1016/S0960-8524(03)00064-6.
[16]  Jankowska, H.; Swaiatkowski, A.; Choma, J. Activated Carbon; Ellis Horwood: New York, NY, USA, 1991.
[17]  Tofighy, M.A.; Mohammadi, T. Adsorption of divalent heavy metal ions from water using carbon nanotube sheets. J. Hazard. Mater. 2011, 185, 140–147, doi:10.1016/j.jhazmat.2010.09.008.
[18]  González, J.F.; Román, S.; Encinar, J.M.; Martínez, G. Pyrolysis of various biomass residues and char utilization for the production of activated carbons. J. Anal. Appl. Pyrol. 2009, 85, 134–141, doi:10.1016/j.jaap.2008.11.035.
[19]  Babel, S.; Kurniawan, T.A. Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan. Chemosphere 2004, 54, 951–967, doi:10.1016/j.chemosphere.2003.10.001.
[20]  Nomanbhay, S.M.; Palanisamy, K. Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal. Electron. J. Biotechnol. 2005, 8, 43–53.
[21]  Li, Y.; Du, Q.; Wang, X.; Zhang, P.; Wang, D.; Wang, Z.; Xia, Y. Removal of lead from aqueous solution by activated carbon prepared from Enteromorpha prolifera by zinc chloride activation. J. Hazard. Mater. 2010, 183, 583–589, doi:10.1016/j.jhazmat.2010.07.063.
[22]  Amuda, O.S.; Giwa, A.A.; Bello, I.A. Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochem. Eng. J. 2007, 36, 174–181, doi:10.1016/j.bej.2007.02.013.
[23]  Aroua, M.K.; Leong, S.P.P.; Teo, L.Y.; Yin, C.Y.; Daud, W.M.A.W. Real-time determination of kinetics of adsorption of lead(II) onto palm shell-based activated carbon using ion selective electrode. Bioresour. Technol. 2008, 99, 5786–5792, doi:10.1016/j.biortech.2007.10.010.
[24]  Mohamed, A.S.; Ghalia, A.Z.; Samia, A.K. Simultaneous removal of copper(II), lead(II), zinc(II) and cadmium(II) from aqueous solutions by multi-walled carbon nanotubes. C. R. Chim. 2012, 15, 398–408, doi:10.1016/j.crci.2012.01.013.
[25]  Imamoglu, M.; Tekir, O. Removal of copper(II) and lead(II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 2008, 228, 108–113, doi:10.1016/j.desal.2007.08.011.
[26]  Gong, J.; Liu, T.; Wang, X.; Hu, X.; Zhang, L. Efficient removal of heavy metal ions from aqueous systems with the assembly of anisotropic layered double hydroxide nanocrystals@carbon nanosphere. Environ. Sci. Technol. 2011, 45, 6181–6187, doi:10.1021/es200668q.
[27]  Liu, J.; Wang, X. Novel silica-based hybrid adsorbents: Lead(II) adsorption isotherms. Sci. World J. 2013, 2013. Article 897159.
[28]  Shahmohammadi-Kalalagh, S.; Babazadeh, H.; Nazemi, A.H.; Manshouri, M. Isotherm and kinetic studies on adsorption of Pb, Zn and Cu by kaolinite. Caspian J. Environ. Sci. 2011, 9, 243–255.
[29]  Mom?ilovi?, M.; Purenovi?, M.; Boji?, A.; Zarubica, A.; Ran?elovi?, M. Removal of lead(II) ions from aqueous solutions by adsorption onto pine cone activated carbon. Desalination 2011, 276, 53–59, doi:10.1016/j.desal.2011.03.013.
[30]  Issabayeva, G.; Aroua, M.K.; Sulaiman, N.M.N.S. Removal of lead from aqueous solutions on palm shell activated carbon. Bioresour. Technol. 2006, 97, 2350–2355, doi:10.1016/j.biortech.2005.10.023.
[31]  Kobya, M.; Demirbas, E.; Senturk, E.; Ince, M. Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. Bioresour. Technol. 2005, 96, 1518–1521, doi:10.1016/j.biortech.2004.12.005.
[32]  Figaro, S.; Avril, J.P.; Brouers, F.; Ouensanga, A.; Gaspard, S. Adsorption studies of molasse’s wastewaters on activated carbon: Modelling with a new fractal kinetic equation and evaluation of kinetic models. J. Hazard. Mater. 2009, 161, 649–656, doi:10.1016/j.jhazmat.2008.04.006.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133