全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
Foods  2013 

Phenolic Extracts from Wild Olive Leaves and Their Potential as Edible Oils Antioxidants

DOI: 10.3390/foods2010018

Keywords: antioxidants, extraction kinetics, oil protection, phenolics, supercritical fluid extraction

Full-Text   Cite this paper   Add to My Lib

Abstract:

The kinetics solid-liquid extraction of phenolics from wild olive leaves was elaborated using different mathematical models (Peleg, second order, Elovich, and power law model). As solvents, methanol, ethanol, ethanol:water 1:1, n-propanol, isopropanol and ethyl acetate were used. The second order model best described the solvent extraction process, followed by the Elovich model. The most effective solvent was ethanol with optimum phenol extraction conditions 180 min, solvent to sample ratio 5:1 v/w and pH 2. Ethanol extract exhibited the highest antiradical activity among solvent and supercritical fluid extraction (SFE) extracts, which in addition showed the highest antioxidant capacity compared to synthetic and natural food antioxidants such as BHT, ascorbyl palmitate and vitamin E. Antioxidant potential of SFE extract was quite high, although its phenolic potential was not. Leaf extracts were proven to be good protectors for olive and sunflower oils at levels of 150 ppm.

References

[1]  De Leonardis, A.; Aretini, A.; Alfano, G.; Macciola, V.; Ranalli, G. Isolation of a hydroxytyrosol-rich extract from olive leaves (Olea Europaea L.) and evaluation of its antioxidant properties and bioactivity. Eur. Food Res. Technol. 2008, 226, 653–659.
[2]  Fki, I.; Allouche, N.; Sayadi, S. The use of polyphenolic extract, purified hydroxytyrosol and 3,4-dihydroxyphenyl acetic acid from olive mill wastewater for the stabilization of refined oils: A potential alternative to synthetic antioxidants. Food Chem. 2005, 93, 197–204, doi:10.1016/j.foodchem.2004.09.014.
[3]  Guinda, á. Use of solid residue from the olive industry. Grasas Y Aceites 2006, 57, 107–115.
[4]  Lafka, T.-I.; Lazou, A.E.; Sinanoglou, V.J.; Lazos, E.S. Phenolic and antioxidant potential of olive oil mill wastes. Food Chem. 2011, 125, 92–98, doi:10.1016/j.foodchem.2010.08.041.
[5]  Taamalli, A.; Arráez-Román, D.; Zarrouk, M.; Valverde, J.; Segura-Carretero, A.; Fernández-Gutiérrez, A. The occurrence and bioactivity of polyphenols in Tunisian olive products and by-products: A review. J. Food Sci. 2012, 77, R83–R92, doi:10.1111/j.1750-3841.2011.02599.x.
[6]  Fares, R.; Bazzi, S.; Baydoun, S.; Abdel-Massih, R.M. The antioxidant and anti-proliferative activity of the Lebanese Olea europaea extract. Plant Foods Hum. Nutr. 2011, 66, 58–63, doi:10.1007/s11130-011-0213-9.
[7]  Massei, G.; Hartley, S.E. Disarmed by domestication? Induced responses to browsing in wild and cultivated olive. Oecologia 2000, 122, 225–231, doi:10.1007/PL00008850.
[8]  Abaza, L.; Youssef, N.B.; Manai, H.; Haddada, F.M.; Methenni, K.; Zarrouk, M. Chétoui olive leaf extracts: Influence of the solvent type on phenolics and antioxidant activities. Grasas Y Aceites 2011, 62, 96–104, doi:10.3989/gya.044710.
[9]  Chirinos, R.; Rogez, H.; Campos, D.; Pedreschi, R.; Larondelle, Y. Optimization of extraction conditions of antioxidant phenolic compounds from mashua (Tropaeolum tuberosum Ruíz & Pavón) tubers. Sep. Purif. Technol. 2007, 55, 217–225, doi:10.1016/j.seppur.2006.12.005.
[10]  Lafka, T.-I.; Sinanoglou, V.; Lazos, E.S. On the extraction and antioxidant activity of phenolic compounds from winery wastes. Food Chem. 2007, 104, 1206–1214, doi:10.1016/j.foodchem.2007.01.068.
[11]  Le Floch, F.; Tena, M.T.; Ríos, A.; Valcárcel, M. Supercritical fluid extraction of phenol compounds from olive leaves. Talanta 1998, 46, 1123–1130, doi:10.1016/S0039-9140(97)00375-5.
[12]  ahin, S.; Bilgin, M. Study on oleuropein extraction from olive tree (Olea europaea) leaves by means of SFE: Comparison of water and ethanol as co-solvent. Sep. Sci. Technol. 2012, 47, 2391–2398.
[13]  Association of Official Analytical Chemists (AOAC). Official Methods of Analysis of the Association of Official Analytical Chemists International, 16th ed.; AOAC: Arlington, VA, USA, 1995.
[14]  Gutfinger, T. Polyphenols in olive oils. J. Am. Oil Chem. Soc. 1981, 58, 966–968, doi:10.1007/BF02659771.
[15]  Bandonien?, D.; Murkovic, M.; Pfannhauser, W.; Venskutonis, P.R.; Gruzdien?, D. Detection and activity evaluation of radical scavenging compounds by using DPPH free radical and on-line HPLC-DPPH methods. Eur. Food Res. Technol. 2002, 214, 143–147, doi:10.1007/s00217-001-0430-9.
[16]  EEC. Characteristics of olive and olive-pomance oils and their analytical methods. Regulation EEC/2568/1991. Off. J. Eur. Communities 1991, L248, 1–82.
[17]  Peleg, M. An empirical model for the description of moisture sorption curves. J. Food Sci. 1988, 53, 1216–1217, doi:10.1111/j.1365-2621.1988.tb13565.x.
[18]  Amendola, D., de Faveri; Spigno, G. Grape marc phenolics: Extraction kinetics, quality and stability of extracts. J. Food Eng. 2010, 97, 384–392.
[19]  Buci?-Koji?, A.; Planini?, M.; Tomas, S.; Bili?, M.; Veli?, D. Study of solid-liquid extraction kinetics of total polyphenols from grape seeds. J. Food Eng. 2007, 81, 236–242, doi:10.1016/j.jfoodeng.2006.10.027.
[20]  Bouaziz, M.; Sayadi, S. Isolation and evaluation of antioxidants from leaves of a Tunisian cultivar olive tree. Eur. J. Lipid Sci. Technol. 2005, 107, 497–504, doi:10.1002/ejlt.200501166.
[21]  Kiritsakis, K.; Kontominas, M.G.; Kontogiorgis, C.; Hadjipavlou-Litina, D.; Moustakas, A.; Kiritsakis, A. Composition and antioxidant activity of olive leaf extracts from Greek olive cultivars. J. Am. Oil Chem. Soc. 2010, 87, 369–376, doi:10.1007/s11746-009-1517-x.
[22]  Kontogianni, V.G.; Gerothanassis, I.P. Phenolic compounds and antioxidant activity of olive leaf extracts. Nat. Prod. Res. 2011, 26, 186–189.
[23]  Benavente-García, O.; Castillo, J.; Lorente, J.; Ortu?o, A.; Del Rio, J.A. Antioxidant activity of phenolics extracted from Olea europaea L. leaves. Food Chem. 2000, 68, 457–462, doi:10.1016/S0308-8146(99)00221-6.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133