We review recent progress in the development of high birefringence (Δ n ≥ 0.12) negative dielectric anisotropy (Δ ε < 0) liquid crystals (LCs) for direct-view and projection displays. For mobile displays, our UCF-N2 (low viscosity, negative Δ ε, high Δ n) based homogeneous alignment fringe-field switching (called n-FFS) mode exhibits superior performance to p-FFS in transmittance, single gamma curve, cell gap insensitivity, and negligible flexoelectric effect. For projection displays using a vertical alignment liquid-crystal-on-silicon (VA LCOS), our high birefringence UCF-N3 mixture enables a submillisecond gray-to-gray response time, which is essential for color sequential displays without noticeable color breakup. Our low viscosity UCF-N2 also enables multi-domain VA displays to use a thinner cell gap for achieving faster response time.
References
[1]
Kirsch, P.; Heckmeier, M.; Tarumi, K. Design and synthesis of nematic liquid crystals with negative dielectric anisotropy. Liq. Cryst. 1999, 26, 449–452, doi:10.1080/026782999205236.
[2]
Kirsch, P.; Reiffenrath, V.; Bremer, M. Nematic liquid crystals with negative dielectric anisotropy: Molecular design and synthesis. Synlett 1999, 1999, 389–396, doi:10.1055/s-1999-2619.
[3]
Klasen, M.; Bremer, M.; Tarumi, K. New liquid-crystal materials for active matrix displays with negative dielectric anisotropy and low rotational viscosity. Jpn. J. Appl. Phys. 2000, 39, L1180–L1182, doi:10.1143/JJAP.39.1180.
[4]
Kirsch, P.; Tarumi, K. A novel type of liquid crystals based on axially fluorinated cyclohexane units. Angew. Chem. Int. Ed. 1998, 37, 484–489, doi:10.1002/(SICI)1521-3773(19980302)37:4<484::AID-ANIE484>3.0.CO;2-6.
[5]
Schadt, M. Liquid crystal materials and liquid crystal displays. Annu. Rev. Mater. Sci. 1997, 27, 305–379, doi:10.1146/annurev.matsci.27.1.305.
[6]
Hird, M.; Goodby, J.W.; Toyne, K.J. Nematic materials with negative dielectric anisotropy for display applications. Proc. SPIE 2000, 3955, 15–23, doi:10.1117/12.379979.
[7]
Ogata, M.; Ukai, K.; Kawai, T. Visual fatigue in congenital nystagmus caused by viewing images of color sequential projectors. J. Disp. Technol. 2005, 1, 314–320, doi:10.1109/JDT.2005.858918.
[8]
Chen, Y.; Sun, J.; Xianyu, H.; Wu, S.T.; Liang, X.; Tang, H. High birefringence fluoro-terphenyls for thin-cell-gap TFT-LCDs. J. Disp. Technol. 2011, 7, 478–481, doi:10.1109/JDT.2011.2150197.
[9]
Hird, M. Fluorinated liquid crystals—Properties and applications. Chem. Soc. Rev. 2007, 36, 2070–2095, doi:10.1039/b610738a.
[10]
Gray, G.W.; Hird, M.; Toyne, K.J. The synthesis of several lateral difluoro-substituted 4,4′′-dialkyl- and 4,4′′-alkoxyalkyl-terphenyls and a rationalisation of the effect of such substitution on mesophase type and transition temperatures. Mol. Cryst. Liq. Cryst. 1991, 204, 43–64, doi:10.1080/00268949108046593.
[11]
Wu, S.T.; Hsu, C.S.; Chen, J.M. Room temperature difluoro-tolane and diphenyl-diacetylene liquid crystals with negative dielectric anisotropy. Mol. Cryst. Liq. Cryst. 1997, 304, 441–445, doi:10.1080/10587259708046994.
Oh-e, M.; Kondo, K. Electro-optical characteristics and switching behavior of the in-plane switching mode. Appl. Phys. Lett. 1995, 67, 3895–3897, doi:10.1063/1.115309.
[15]
Lee, S.H.; Lee, S.L.; Kim, H.Y. Electro-optic characteristics and switching principle of a nematic liquid crystal cell controlled by fringe-field switching. Appl. Phys. Lett. 1998, 73, 2881–2883, doi:10.1063/1.122617.
[16]
Chen, Y.; Luo, Z.; Peng, F.; Wu, S.T. Fringe-field wwitching with a negative dielectric anisotropy liquid crystal. J. Disp. Technol. 2013, 9, 74–77, doi:10.1109/JDT.2013.2242844.
[17]
Yun, H.J.; Jo, M.H.; Jang, I.W.; Lee, S.H.; Ahn, S.H.; Hur, H.J. Achieving high light efficiency and fast response time in fringe field switching mode using a liquid crystal with negative dielectric anisotropy. Liq. Cryst. 2012, 39, 1141–1148, doi:10.1080/02678292.2012.700078.
[18]
Schiekel, M.F.; Fahrenschon, K. Deformation of nematic liquid crystals with vertical orientation in electrical fields. Appl. Phys. Lett. 1971, 19, 391–393, doi:10.1063/1.1653743.
[19]
Kahn, F.J. Electric-field-induced orientational deformation of nematic liquid-crystals: Tunable birefringence. Appl. Phys. Lett. 1972, 20, 199–201, doi:10.1063/1.1654107.
[20]
Takeda, A.; Kataoka, S.; Sasaki, T.; Chida, H.; Tsuda, H.; Ohmuro, K.; Sasabayashi, T.; Koike, Y.; Okamoto, K. A super-high image quality multi-domain vertical alignment LCD by new rubbing-less technology. SID Symp. Dig. Tech. Pap. 1998, 29, 1077–1080, doi:10.1889/1.1833672.
[21]
Ohmuro, K.; Kataoka, S.; Sasaki, T.; Koike, Y. Development of super-high-image-quality vertical-alignment-mode LCD. SID Int. Symp. Dig. Tech. Pap. 1997, 28, 845–850.
[22]
Cuypers, D.; De Smet, H.; Van Calster, A. VAN LCOS microdisplays: A decade of technological evolution. J. Disp. Technol. 2011, 7, 127–134, doi:10.1109/JDT.2010.2053018.
[23]
Khoo, I.C.; Wu, S.T. Optics and Nonlinear Optics of Liquid Crystals; World Scientific: Singapore, 1993.
[24]
Yang, D.K.; Wu, S.T. Fundamentals of Liquid Crystal Devices; Wiley: New York, NY, USA, 2006.
[25]
Wu, S.T.; Wu, C.S. Small angle relaxation of highly deformed nematic liquid crystals. Appl. Phys. Lett. 1988, 53, 1794–1796, doi:10.1063/1.99783.
Wu, S.T. Nematic liquid crystal modulator with response time less than 100 μs at room temperature. Appl. Phys. Lett. 1990, 57, 986–988, doi:10.1063/1.103533.
Blinov, L.M.; Chigrinov, V.G. Electrooptic Effects in Liquid Crystal Materials; Springer-Verlag: New York, NY, USA, 1994.
[35]
Lee, J.H.; Park, K.H.; Kim, S.H.; Choi, H.C.; Kim, B.K.; Yin, Y. AH-IPS: Superb display for mobile device. SID Symp. Dig. Tech. Pap. 2013, 44, 32–33, doi:10.1002/j.2168-0159.2013.tb06132.x.
Clark, M.G.; Raynes, E.P.; Smith, R.A.; Tough, R.J.A. Measurement of the permittivity of nematic liquid-crystals in magnetic and electric-fields using extrapolation procedures. J. Phys. D Appl. Phys. 1980, 13, 2151:1–2151:11.
[38]
Wu, S.T.; Wu, C.S. Experimental confirmation of the Osipov-Terentjev theory on the viscosity of nematic liquid-crystals. Phys. Rev. A 1990, 42, 2219–2227, doi:10.1103/PhysRevA.42.2219.
Haller, I. Thermodynamic and static properties of liquid crystals. Prog. Solid State Chem. 1975, 10, 103–118, doi:10.1016/0079-6786(75)90008-4.
[41]
Wu, S.T. Birefringence dispersions of liquid-crystals. Phys. Rev. A 1986, 33, 1270–1274, doi:10.1103/PhysRevA.33.1270.
[42]
Wu, S.T.; Lackner, A.M.; Efron, U. Optimal operation temperature of liquid-crystal modulators. Appl. Opt. 1987, 26, 3441–3445, doi:10.1364/AO.26.003441.
[43]
Lien, A. Extended Jones Matrix representation for the twisted nematic liquid-crystal display at oblique-incidence. Appl. Phys. Lett. 1990, 57, 2767–2769, doi:10.1063/1.103781.
[44]
Ge, Z.B.; Wu, S.T.; Kim, S.S.; Park, J.W.; Lee, S.H. Thin cell fringe-field-switching liquid crystal display with a chiral dopant. Appl. Phys. Lett. 2008, 92, 181109:1–181109:3.
[45]
Hong, S.H.; Park, I.C.; Kim, H.Y.; Lee, S.H. Electro-optic characteristic of fringe-field switching mode depending on rubbing direction. Jpn. J. Appl. Phys. 2000, 39, L527–L530.
Fan-Chiang, K.H.; Wu, S.T.; Chen, S.H. Fringing-field effects on high-resolution liquid crystal microdisplays. J. Disp. Technol. 2005, 1, 304–313, doi:10.1109/JDT.2005.858930.
[57]
Wang, H.; Wu, T.X.; Zhu, X.; Wu, S.T. Correlations between liquid crystal director reorientation and optical response time of a homeotropic cell. J. Appl. Phys. 2004, 95, 5502–5508, doi:10.1063/1.1707210.
[58]
Chen, Y.; Peng, F.; Wu, S.T. Submillisecond-response vertical-aligned liquid crystal for color sequential projection displays. J. Disp. Technol. 2013, 9, 78–81, doi:10.1109/JDT.2013.2243403.
[59]
Wen, C.H.; Gauza, S.; Wu, S.T. Photostability of liquid crystals and alignment layers. J. Soc. Inf. Disp. 2005, 13, 805–811, doi:10.1889/1.2080522.
[60]
Kim, S.S. The world’s largest (82-in) TFT-LCD. SID Symp. Dig. Tech. Pap. 2005, 36, 1842–1847, doi:10.1889/1.2036378.
[61]
Miyachi, K.; Kobayashi, K.; Yamada, Y.; Mizushima, S. The world’s first photo alignment LCD technology applied to Generation Ten factory. SID Symp. Dig. Tech. Pap. 2010, 41, 579–582, doi:10.1889/1.3500533.
[62]
Lee, S.H.; Kim, S.M.; Wu, S.T. Emerging vertical-alignment liquid-crystal technology associated with surface modification using UV-curable monomer. J. Soc. Inf. Disp. 2009, 17, 551–559, doi:10.1889/JSID17.7.551.
[63]
Hong, H.; Shin, H.; Chung, I. In-plane switching technology for liquid crystal display television. J. Disp. Technol. 2007, 3, 361–370, doi:10.1109/JDT.2007.901562.