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Coatings  2013 

Fabrication of Nanodiamond Coating on Steel

DOI: 10.3390/coatings3040243

Keywords: diamond coating on steel, CrN, hot filament chemical vapor deposition, nanocrystalline diamond, microcrystalline diamond, carbon nanotubes

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Abstract:

The hardness, heat conductivity and low friction coefficient of microcrystalline diamond make it a suitable candidate for tribological applications. However, its roughness and high deposition temperature pose significant obstacles to these applications. We have successfully grown nanocrystalline diamond on steel at 400 °C by hot-filament chemical vapor deposition by employing a CrN interfacial layer. Nanocrystalline diamond combines hardness and surface smoothness required in tribological applications. Microcrystalline diamond and carbon nanotubes can also be grown by controlling the deposition parameters. The fabricated films were characterized with Raman spectroscopy, X-ray diffraction (XRD), Transmission electron microscopy (TEM), and scanning electron microscopy (SEM).

References

[1]  Neto, V.F.; Vaz, R.; Ali, N.; Oliveira, M.S.A.; Grácio, J.; Ghumman, C.A.A.; Teodoro, O.M.N.D. Carbon diffusion into steel during diamond chemical vapour deposition. Int. J. Nanomanufacturing 2008, 2, 192–203, doi:10.1504/IJNM.2008.018945.
[2]  Chen, H.; Nielsen, M.L.; Gold, C.J.; Dillon, R.O.; DiGregorio, J.; Furtak, T. Growth of diamond films on stainless steel. Thin Solid Films 1992, 212, 169–172, doi:10.1016/0040-6090(92)90516-E.
[3]  Fenker, M.; Ferber, H.; Fü?er, H.-J.; J?rgensen, G.; Lahres, M.; Wolf, G.K. Deposition of CVD diamond onto ion beam modified ASP 23 cutting tools. Surf. Coatings Technol. 1998, 98, 1053–1059, doi:10.1016/S0257-8972(97)00230-2.
[4]  Buijnsters, J.G.; Shankar, P.; van Enckevort, W.J.P.; Schermer, J.J.; ter Meulen, J.J. The applicability of ultra thin silicon films as interlayers for CVD diamond deposition on steels. Phys. Stat. Sol. A 2003, 195, 383–395, doi:10.1002/pssa.200305947.
[5]  Klages, C.-P.; Fryda, M.; Matthke, T.; Sch?fer, L.; Dimigen, H. Diamond coatings and cBN coatings for tools. Int. J. Refract. Met. Hard Mater. 1998, 16, 171–176, doi:10.1016/S0263-4368(98)80100-5.
[6]  Sch?fer, L.; Fryda, M.; Stolley, T.; Xiang, L.; Klages, C.-P. Chemical vapour deposition of polycrystalline diamond films on high-speed steel. Surf. Coatings Technol. 1999, 116–119, 447–451, doi:10.1016/S0257-8972(99)00102-4.
[7]  Ralchenko, V.G.; Smolin, A.A.; Pereverzev, V.G.; Obraztsova, E.D.; Korotoushenko, K.G.; Konov, V.I.; Lakhotkin, Y.V.; Loubnin, E.N. Diamond deposition on steel with CVD tungsten intermediate layer. Diam. Relat. Mater. 1995, 4, 754–758.
[8]  Haubner, R.; Lux, B. Diamond deposition on steel substrates using intermediate layers. Int. J. Refract. Met. Hard Mater. 2006, 24, 380–386, doi:10.1016/j.ijrmhm.2005.11.008.
[9]  Weiser, P.S.; Prawer, S. Chemical vapour deposition of diamond onto iron based substrates—The use of barrier layers. Diam. Relat. Mater. 1995, 4, 710–713, doi:10.1016/0925-9635(94)05269-7.
[10]  Lorenz, H.P. Investigation of TiN as an interlayer for diamond deposition on steel. Diam. Relat. Mater. 1995, 4, 1088–1092, doi:10.1016/0925-9635(95)00282-0.
[11]  Fan, Q.H.; Fernandes, A.; Gracio, J. Diamond coating on steel with a titanium interlayer. Diam. Relat. Mater. 1998, 7, 603–606, doi:10.1016/S0925-9635(97)00287-2.
[12]  Fan, Q.H.; Fernandes, A.; Pereira, E.; Grácio, J. Adhesion of diamond coatings on steel and copper with a titanium interlayer. Diam. Relat. Mater. 1999, 8, 1549–1554, doi:10.1016/S0925-9635(99)00064-3.
[13]  Silva, F.J.G.; Baptista, A.P.M.; Pereira, E.; Teixeira, V.; Fan, Q.H.; Fernandes, A.J.S.; Costa, F.M. Microwave plasma chemical vapour deposition diamond nucleation on ferrous substrates with Ti and Cr interlayers. Diam. Relat. Mater. 2002, 11, 1617–1622, doi:10.1016/S0925-9635(02)00029-8.
[14]  Polini, R.; Mantini, F.P.; Braic, M.; Amar, M.; Ahmed, W.; Taylor, H. Effects of Ti- and Zr-based interlayer coatings on the hot filament chemical vapour deposition of diamond on high speed steel. Thin Solid Films 2006, 494, 116–122, doi:10.1016/j.tsf.2005.08.219.
[15]  Lin, C.R.; Kuo, C.T. High adhesion and quality diamond films on steel substrate. Diam. Relat. Mater. 1998, 7, 903–907, doi:10.1016/S0925-9635(97)00327-0.
[16]  Borges, C.F.M.; Pfender, E.; Heberlein, J. Influence of nitrided and carbonitrided interlayers on enhanced nucleation of diamond on stainless steel 304. Diam. Relat. Mater. 2001, 10, 1983–1990, doi:10.1016/S0925-9635(01)00465-4.
[17]  Bareiβ, C.; Perle, M.; Rosiwal, S.M.; Singer, R.F. Diamond coating of steel at high temperatures in hot filament chemical vapour deposition (HFCVD) employing chromium interlayers. Diam. Relat. Mater. 2006, 15, 754–760, doi:10.1016/j.diamond.2005.10.053.
[18]  Schwarz, S.; Musayev, Y.; Rosiwal, S.M.; Schaufler, C.; Singer, R.F.; Meerkamm, H. Diam. Relat. Mater. 2002, 11, 757–762, doi:10.1016/S0925-9635(01)00710-5.
[19]  Schwarz, S.; Rosiwal, S.M.; Musayev, Y.; Singer, R.F. High temperature diffusion chromizing as a successful method for CVD-diamond coating of steel—Part II. Diam. Relat. Mater. 2003, 12, 701–706.
[20]  Fayer, A.; Glozman, O.; Hoffman, A. Deposition of continuous and well adhering diamond films on steel. Appl. Phys. Lett. 1995, 67, 2299–2301, doi:10.1063/1.115132.
[21]  Glozman, O.; Berner, A.; Shechtman, D.; Hoffman, A. Influence of Cr-N interlayer properties on the initial stages of CVD diamond growth on steel substrates. Diam. Relat. Mater. 1998, 7, 597–602.
[22]  Glozman, O.; Halperin, G.; Etsion, I.; Berner, A.; Shectman, D.; Lee, G.H.; Hoffman, A. Study of the wear behavior and adhesion of diamond films deposited on steel substrates by use of a Cr–N interlayer. Diam. Relat. Mater. 1999, 8, 859–864, doi:10.1016/S0925-9635(98)00321-5.
[23]  Glozman, O.; Hoffman, A. Adhesion improvement of diamond films on steel subtrates using chromium nitride interlayers. Diam. Relat. Mater. 1997, 6, 796–801, doi:10.1016/S0925-9635(96)00671-1.
[24]  Avigal, Y.; Glozman, O.; Etsion, I.; Halperin, G.; Hoffman, A. [100]-Textured diamond films for tribological applications. Diam. Relat. Mater. 1997, 6, 381–385, doi:10.1016/S0925-9635(96)00625-5.
[25]  Buijnsters, J.G.; Shankar, P.; Fleischer, W.; van Enckevort, W.J.P.; Schermer, J.J.; ter Meulen, J.J. CVD diamond deposition on steel using arc-plated chromium nitride interlayers. Diam. Relat. Mater. 2002, 11, 536–544, doi:10.1016/S0925-9635(01)00628-8.
[26]  Silva, F.J.G.; Fernandes, A.J.S.; Costa, F.M.; Baptista, A.P.M.; Pereira, E. A new interlayer approach for CVD diamond coating of steel substrates. Diam. Relat. Mater. 2004, 13, 828–833, doi:10.1016/j.diamond.2003.10.081.
[27]  Silva, F.J.G.; Fernandes, A.J.S.; Costa, F.M.; Teixeira, V.; Baptista, A.P.M.; Pereira, E. Tribological behaviour of CVD diamond films on steel substrates. Wear 2003, 255, 846–853, doi:10.1016/S0043-1648(03)00145-5.
[28]  Silva, F.J.G.; Fernandes, A.J.S.; Costa, F.M.; Baptista, A.P.M.; Pereira, E. Unstressed PACVD diamond films on steel pre-coated with a composite multilayer. Surf. Coatings Technol. 2005, 191, 102–107, doi:10.1016/j.surfcoat.2004.02.036.
[29]  Gupta, S.; Weiss, B.L.; Weiner, B.R.; Morell, G. Study of the electron field emission and microstructure correlation in nanocrystalline carbon thin films. J. Appl. Phys. 2001, 89, 5671–5675.
[30]  Piazza, F.; Gonzalez, J.A.; Velazquez, R.; De Jesus, J.; Rosario, S.A.; Morell, G. Diamond film synthesis at low temperature. Diam. Relat. Mater. 2006, 15, 109–116, doi:10.1016/j.diamond.2005.07.028.
[31]  Ferrari, A.C.; Robertson, J. Raman spectroscopy of amorphous, nanostructured, diamond-like carbon, and nanodiamond. Phil. Trans. R. Soc. Lond. A 2004, 362, 2477–2512.
[32]  Islam, S.S.; Shah, K.A.; Mavi, H.S.; Shaukla, A.K.; Rath, S.; Harsh, S. Raman study on single-walled carbon nanotubes with different laser excitation energies. Bull. Mater. Sci. 2007, 30, 295–299.
[33]  Bandow, S.; Asaka, S.; Saito, Y.; Rao, A.M.; Grigorian, L.; Richter, E.; Eklund, P.C. Effect of the growth temperature on the diameter distribution and chirality of single-wall carbon nanotubes. Phys. Rev. Lett. 1998, 80, 3779–3782.
[34]  Kobayashi, Y.; Takayuki, T.; Ueno, Y.; Niwa, O.; Homma, Y.; Ogino, T. Extremely intense Raman signals from single-walled carbon nanotubes suspended between Si nanopillars. Chem. Phys. Lett. 2004, 386, 153–157.
[35]  Wei, J.; Yung, K.P.; Tay, B.K. Formation of CNT bumps for interconnection applications. SIMTech Tech. Rep. 2009, 10, 76–79.
[36]  Uebing, C.; Viefhaus, H.; Grabke, H.J. Formation of CrN surface compounds and surface precipitates on Fe-15%Cr-N single crystals. Appl. Surf. Sci. 1988, 32, 363–380, doi:10.1016/0169-4332(88)90088-8.
[37]  Martin-Gil, J.; Matin-Gil, F.J.; Sarikaya, M.; Qian, M.; Jose-Yacaman, M.; Rubio, A. Evidence of a low compressibility carbon nitride with defect-zincblende structure. J. Appl. Phys. 1997, 81, 2555–2559.
[38]  Keller, T.M.; Laskoski, M.; Osofsky, M.; Qadri, S.B. Carbon nanotube formation catalyzed by Ni nanoparticles in carbonaceous solid. Phys. Stat. Sol. A 2008, 205, 1585–1591.
[39]  Neto, V.F.; Vaz, R.; Oliveira, M.S.A.; Grácio, J. CVD diamond-coated steel inserts for thermoplastic mould tools—Characterization and preliminary performance evaluation. J. Mater. Process. Technol. 2009, 209, 1085–1091.
[40]  Neto, V.F.; Vaz, R.; Ali, N.; Oliveira, M.S.A.; Grácio, J. Performance of sub-micron diamond films coated on mould inserts for plastic injection moulding. J. Mater. Sci. 2008, 43, 3392–3399.
[41]  Neto, V.F.; Vaz, R.; Ali, N.; Oliveira, M.S.A.; Grácio, J. Diamond coatings on 3D structured steel. Diam. Relat. Mater. 2008, 17, 1424–1428, doi:10.1016/j.diamond.2008.01.113.
[42]  Neto, V.F.; Oliveira, M.S.A.; Ali, N.; Grácio, J. Time-modulated chemical vapour deposition diamonf on mould making 2738 steel. Vacuum 2008, 82, 1346–1349, doi:10.1016/j.vacuum.2008.03.041.
[43]  Haubner, R.; Sommer, D. Hot-filament diamond deposition with sulfur addition. Diam. Relat. Mater. 2003, 12, 298–305, doi:10.1016/S0925-9635(02)00342-4.
[44]  Oberlin, A. Carbonization and graphitization. Carbon 1984, 22, 521–541, doi:10.1016/0008-6223(84)90086-1.

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