全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Equilibrium, Kinetics, and Thermodynamics of Remazol Brilliant Blue R Dye Adsorption onto Activated Carbon Prepared from Pinang Frond

DOI: 10.1155/2014/184265

Full-Text   Cite this paper   Add to My Lib

Abstract:

The adsorption of remazol brilliant blue R (RBBR) dye on pinang frond based activated carbon (PF-AC) was investigated in a batch process. The effects of initial dye concentration, contact time, solution temperature, and solution pH were evaluated. The adsorption equilibrium and kinetic were found to follow Freundlich isotherm models and pseudo-second-order kinetic model, respectively. The mechanism of the adsorption process was found from the intraparticle diffusion model. Result from adsorption thermodynamic show that interaction for RBBR dye was found to be feasible, nonspontaneous, and endothermic. The results indicated that the PF-AC is very effective for the RBBR adsorption from aqueous solution. 1. Introduction Around 10,000 different dyes are produced annually from various industrial process which weigh approximately 0.7 million tons [1]. Dyes have a synthetic origin and complex aromatic molecular structures. It is estimated that 10–15% of the dyes are lost in the effluent during dyeing process [2]. In the textile industry, effluents from the dyeing and finishing processes are known to contain colour, a large amount of suspended organic solids and possibly heavy metals such as Cr, Ni, and Cu [3]. Dyes are inert and difficult to biodegrade and decolorize when discharged into waste streams. Hence, the presence of dyes into streams and rivers constitutes a source of water pollution that cannot be neglected [4]. In textile industry, there are several varieties of dyes used such as reactive dyes, direct dyes, disperse dyes, acid dyes, basic dyes, and vat dyes. Almost 45% of textile produced worldwide belongs to the reactive dyes [5]. Remazol brilliant blue R (RBBR), remazol black (RB), and remazol brilliant violet 5R (RBV) are the example of reactive dyes. They have the favorable characteristics of bright color, simple application techniques, low energy consumption dyeing process, and high solubility in water. The discharge of these wastewaters reactive dyes into receiving streams are highly carcinogenic and possess toxic to organism [6]. Many studies have been conducted on the toxicity of dyes and their impact on the ecosystem [7, 8]. Therefore, removal of such dyes from wastewater is very important to the environment. Several of successful treatment systems have been designed such as flocculation, coagulation, precipitation, adsorption, membrane filtration, electrochemical techniques, ozonization, sedimentation, reverse osmosis, fungal degradation, and photodegradation [9] but the adsorption onto activated carbon has been found to offer the best

References

[1]  S. Senthilkumaar, P. Kalaamani, K. Porkodi, P. R. Varadarajan, and C. V. Subburaam, “Adsorption of dissolved reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste,” Bioresource Technology, vol. 97, no. 14, pp. 1618–1625, 2006.
[2]  K. Murugesan, I.-H. Nam, Y.-M. Kim, and Y.-S. Chang, “Decolorization of reactive dyes by a thermostable laccase produced by Ganoderma lucidum in solid state culture,” Enzyme and Microbial Technology, vol. 40, no. 7, pp. 1662–1672, 2007.
[3]  E. A. el-Sharkawy, A. Y. Soliman, and K. M. al-Amer, “Comparative study for the removal of methylene blue via adsorption and photocatalytic degradation,” Journal of Colloid and Interface Science, vol. 310, no. 2, pp. 498–508, 2007.
[4]  V. Dulman and S. M. Cucu-Man, “Sorption of some textile dyes by beech wood sawdust,” Journal of Hazardous Materials, vol. 162, no. 2-3, pp. 1457–1464, 2009.
[5]  ?. Tun?, H. Tanaci, and Z. Aksu, “Potential use of cotton plant wastes for the removal of Remazol Black B reactive dye,” Journal of Hazardous Materials, vol. 163, no. 1, pp. 187–198, 2009.
[6]  P. Baskaralingam, M. Pulikesi, V. Ramamurthi, and S. Sivanesan, “Modified hectorites and adsorption studies of a reactive dye,” Applied Clay Science, vol. 37, no. 1-2, pp. 207–214, 2007.
[7]  F. O. Okeola and E. O. Odebunmi, “Freundlich and Langmuir isotherms parameters for adsorption of methylene blue by activated carbon derived from agrowastes,” Advances in Natural and Applied Sciences, vol. 4, no. 3, pp. 281–288, 2010.
[8]  V. Vadivelan and K. V. Kumar, “Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk,” Journal of Colloid and Interface Science, vol. 286, no. 1, pp. 90–100, 2005.
[9]  A. S. Bhatt, P. L. Sakaria, M. Vasudevan et al., “Adsorption of an anionic dye from aqueous medium by organoclays: equilibrium modeling, kinetic and thermodynamic exploration,” RSC Advances, vol. 2, no. 23, pp. 8663–8671, 2012.
[10]  B. H. Hameed, A. L. Ahmad, and K. N. A. Latiff, “Adsorption of basic dye (methylene blue) onto activated carbon prepared from rattan sawdust,” Dyes and Pigments, vol. 75, no. 1, pp. 143–149, 2007.
[11]  M. J. Iqbal and M. N. Ashiq, “Adsorption of dyes from aqueous solutions on activated charcoal,” Journal of Hazardous Materials, vol. 139, no. 1, pp. 57–66, 2007.
[12]  A. ?zcan, E. M. ?ncü, and A. S. ?zcan, “Adsorption of acid blue 193 from aqueous solutions onto DEDMA-sepiolite,” Journal of Hazardous Materials, vol. 129, no. 1–3, pp. 244–252, 2006.
[13]  V. K. Gupta and S. Suhas, “Application of low-cost adsorbents for dye removal—a review,” Journal of Environmental Management, vol. 90, no. 8, pp. 2313–2342, 2009.
[14]  S. G. Herawan, M. A. Ahmad, A. Putra, and A. A. Yusof, “Effect of CO2 flow rate on the pinang frond-based activated carbon for methylene blue removal,” The Scientific World Journal, vol. 2013, Article ID 545948, 6 pages, 2013.
[15]  W.-T. Tsai and H.-R. Chen, “Removal of malachite green from aqueous solution using low-cost chlorella-based biomass,” Journal of Hazardous Materials, vol. 175, no. 1–3, pp. 844–849, 2010.
[16]  M. A. Ahmad and R. Alrozi, “Removal of malachite green dye from aqueous solution using rambutan peel-based activated carbon: equilibrium, kinetic and thermodynamic studies,” Chemical Engineering Journal, vol. 171, no. 2, pp. 510–516, 2011.
[17]  O. S. Bello, M. A. Ahmad, and N. Ahmad, “Adsorptive features of banana (Musa paradisiaca) stalk-based activated carbon for malachite green dye removal,” Chemistry and Ecology, vol. 28, no. 2, pp. 153–167, 2012.
[18]  A. T. M. Din, B. H. Hameed, and A. L. Ahmad, “Batch adsorption of phenol onto physiochemical-activated coconut shell,” Journal of Hazardous Materials, vol. 161, no. 2-3, pp. 1522–1529, 2009.
[19]  B. H. Hameed and M. I. el-Khaiary, “Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: equilibrium isotherms and kinetic studies,” Journal of Hazardous Materials, vol. 154, no. 1–3, pp. 237–244, 2008.
[20]  M. A. Ahmad and N. K. Rahman, “Equilibrium, kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon,” Chemical Engineering Journal, vol. 170, no. 1, pp. 154–161, 2011.
[21]  B. H. Hameed, A. A. Ahmad, and N. Aziz, “Adsorption of reactive dye on palm-oil industry waste: equilibrium, kinetic and thermodynamic studies,” Desalination, vol. 247, no. 1–3, pp. 551–560, 2009.
[22]  A. Ergene, K. Ada, S. Tan, and H. Katircio?lu, “Removal of Remazol Brilliant Blue R dye from aqueous solutions by adsorption onto immobilized Scenedesmus quadricauda: equilibrium and kinetic modeling studies,” Desalination, vol. 249, no. 3, pp. 1308–1314, 2009.
[23]  P. Sathishkumar, M. Arulkumar, and T. Palvannan, “Utilization of agro-industrial waste Jatropha curcas pods as an activated carbon for the adsorption of reactive dye Remazol Brilliant Blue R (RBBR),” Journal of Cleaner Production, vol. 22, no. 1, pp. 67–75, 2012.
[24]  I. Langmuir, “The adsorption of gases on plane surfaces of glass, mica and platinum,” Journal of the American Chemical Society, vol. 40, no. 9, pp. 1361–1403, 1918.
[25]  H. M. F. Freundlich, “Over the adsorption in solution,” The Journal of Physical Chemistry, vol. 385, pp. 385–470, 1906.
[26]  A. ?zcan, ?. ?mero?lu, Y. Erdo?an, and A. S. ?zcan, “Modification of bentonite with a cationic surfactant: an adsorption study of textile dye Reactive Blue 19,” Journal of Hazardous Materials, vol. 140, no. 1-2, pp. 173–179, 2007.
[27]  K. Santhy and P. Selvapathy, “Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon,” Bioresource Technology, vol. 97, no. 11, pp. 1329–1336, 2006.
[28]  A. P. Vieira, S. A. A. Santana, C. W. B. Bezerra et al., “Kinetics and thermodynamics of textile dye adsorption from aqueous solutions using babassu coconut mesocarp,” Journal of Hazardous Materials, vol. 166, no. 2-3, pp. 1272–1278, 2009.
[29]  P. Leechart, W. Nakbanpote, and P. Thiravetyan, “Application of “waste” wood-shaving bottom ash for adsorption of azo reactive dye,” Journal of Environmental Management, vol. 90, no. 2, pp. 912–920, 2009.
[30]  S. Largergren, “Zur theorie der sogenannten adsorption geloster stoffe,” Kungliga Svenska Vetenskapsakademiens Handlingar, vol. 24, pp. 1–39, 1898.
[31]  Y. S. Ho and G. McKay, “Pseudo-second order model for sorption processes,” Process Biochemistry, vol. 34, no. 5, pp. 451–465, 1999.
[32]  B. H. Hameed and M. I. el-Khaiary, “Equilibrium, kinetics and mechanism of malachite green adsorption on activated carbon prepared from bamboo by K2CO3 activation and subsequent gasification with CO2,” Journal of Hazardous Materials, vol. 157, no. 2-3, pp. 344–351, 2008.
[33]  L. Wang, J. Zhang, R. Zhao, C. Li, Y. Li, and C. Zhang, “Adsorption of basic dyes on activated carbon prepared from Polygonum orientale Linn: equilibrium, kinetic and thermodynamic studies,” Desalination, vol. 254, no. 1–3, pp. 68–74, 2010.
[34]  I. A. W. Tan, A. L. Ahmad, and B. H. Hameed, “Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2,4,6-trichlorophenol on oil palm empty fruit bunch-based activated carbon,” Journal of Hazardous Materials, vol. 164, no. 2-3, pp. 473–482, 2009.
[35]  L. Abramian and H. el-Rassy, “Adsorption kinetics and thermodynamics of azo-dye Orange II onto highly porous titania aerogel,” Chemical Engineering Journal, vol. 150, no. 2-3, pp. 403–410, 2009.
[36]  C.-Y. Kuo, C.-H. Wu, and J.-Y. Wu, “Adsorption of direct dyes from aqueous solutions by carbon nanotubes: determination of equilibrium, kinetics and thermodynamics parameters,” Journal of Colloid and Interface Science, vol. 327, no. 2, pp. 308–315, 2008.
[37]  H. Nollet, M. Roels, P. Lutgen, P. van der Meeren, and W. Verstraete, “Removal of PCBs from wastewater using fly ash,” Chemosphere, vol. 53, no. 6, pp. 655–665, 2003.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133