全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Analysis of Essential Elements for Plants Growth Using Instrumental Neutron Activation Analysis

DOI: 10.1155/2013/156520

Full-Text   Cite this paper   Add to My Lib

Abstract:

In this study, a total of ten essential elements for plants growth in the Guinea savanna region of Niger State in Northern Nigeria have been identified in the soils using instrumental neutron activation analysis. The experimental results show good agreement with certified or literature values within the agreed percentage range of ±2.35% to ±8.69%. However, the concentration distributions of the ten identified elements in the soil samples within the studied area for plants growth revealed the following: Fe (123.4?ppm), Mn (2100.7?ppm), K (5544.3?ppm), Al (54752.4?ppm), Ti (3082.9?ppm), Ca (4635?ppm), V (54.3?ppm), Na (857.5?ppm), Mg (13924.1?ppm), and Dy (12.1?ppm). A further analysis of the two fundamental soil physical parameters for healthy growth of some common crops like egusimelon, groundnut, rice, yams, soybeans, cassava, and potato analyzed in this work revealed a pH range of 4.0 pH–8.0 pH and a temperature range of 28.0°C to 29.3°C, which are optimal for plant nutrients availability in the soils within the study area. 1. Introduction Plants require at least sixteen elements for normal growth and completion of their life cycle. They need relatively large amount of nitrogen, phosphorus, and potassium referred to as primary nutrients usually supplied in fertilizers [1]. The three secondary elements Ca, Mg, and S are virtually required in smaller amounts. Ca and Mg are usually supplied with liming materials while S with fertilizer materials [2]. Contaminants in rainfall also supply 4.5?kg to 9.1?kg of nitrogen and sulphur per acre each year depending on the local air quality [3]. The micronutrients consist of seven essential elements which are boron, copper, chlorine, iron, manganese, molybdenum, and zinc. These elements occur in very small amounts in both soil and plants, but their role is as important as the primary nutrients [4, 5]. A deficiency of one or more of the micronutrients can lead to severe depression in growth, yield, and crop quality. Some soils do not contain sufficient amounts of these nutrients to meet the plant’s requirement for rapid growth and good production. In this case, supplemental micronutrients for rapid growth and good yield have to be applied in the form of foliar sprays with adequate knowledge of the elemental concentrations. Thus, this work seeks to analysze the essential elements for plants growth using instrumental neutron activation analysis in seven local government areas (LGAs) of Niger state, namely, Paikoro, Lapai, Mokwa, Katcha, Bida, Agaie, and Suleja local government areas of Niger State. Plants absorb the

References

[1]  S. L. Tisdale, W. L. Nelson, J. D. Beaton, and J. L. Havlin, Soil Fertility and Fertilizer, Prentice Hall, Upper Saddle River, NJ, USA, 5th edition, 1993.
[2]  I. A. Jaiyeoba, “An assessment of soil fertility restoration under fallow in Nigerian savannah,” Soil Use and Management, vol. 13, no. 3, pp. 163–164, 1997.
[3]  C. D. Foy, R. L. Chaney, and M. C. White, “The physiology of metal toxicity in plants,” Annual Review of Plant Physiology, vol. 29, pp. 511–566, 1978.
[4]  V. O. Ajibola and R. Rolawanu, “Trace elements in the environment,” Journal of Scientific and Industrial Research, vol. 59, no. 2, pp. 132–136, 2000.
[5]  A. Aubert and M. Pinta, “Trace elements in soils,” in Development in Soil Science, vol. 7, pp. 43–95, Elsevier, Amsterdam, The Netherlands, 1977.
[6]  I. O. B. Ewa and L. A. Dim, “Major, minor and trace element determinations from a Nigerian aquatic sediment,” Journal of Environmental Science and Health, vol. 24, no. 3, pp. 243–254, 1989.
[7]  S. C. Hodges, Soil Fertility Basics, Soil. Science Extension North Carolina State University Certified Crop Advisor Training, 1995.
[8]  P. A. Sanchez and T. J. Logan, “Myths and scienceabout the chemistry and fertility of soils in the Tropics,” in Myths and Science of Soils of the Tropics, R. Lal and P. A. Sanchez, Eds., pp. 35–46, Soil Science Society of America, Madison, Wis, USA, 1992.
[9]  J. L. Ahlrichs, “The soil environment,” in Organic Chemicals in the Soil Environment, C. A. I. Goring and J. W. Hamaker, Eds., Marcel Dekker, New York, NY, USA, 1972.
[10]  J. O. Adejuwan, “A biogeographical survey of the dynamics of Savannah vegetation in Nigeria,” Geographical Journal, vol. 14, pp. 31–48, 1971.
[11]  I. O. B. Ewa, M. O. A. Oladipo, L. A. Dim, and S. P. Mallam, “Major, minor and trace elements of the Samaru savannah soil in Nigeria,” Journal of Trace and Microprobe Techniques, vol. 18, no. 3, pp. 389–395, 2000.
[12]  J. C. Menaut, R. Barbault, P. Lavelle, and M. Lepage, “African Savannas: biological systems ofhumification and mineralization,” in Ecology and Management of the World’s Savannas, J. C. Tothill and J. J. Mott, Eds., pp. 14–33, Australian Academic Science, Canberra, Australia, 1985.
[13]  I. O. B. Ewa and L. A. Dim, “Major, minor and trace element determinations from a Nigerian aquatic sediment,” Journal of Environmental Science and Health, vol. 24, no. 3, pp. 243–254, 1989.
[14]  V. Y. Borkhodoev, “X-ray fluorescence determination of rubidium, strontium, yttrium, zirconium and niobium in rocks,” Journal of Trace and Microprobe Techniques, vol. 16, no. 3, pp. 341–352, 1998.
[15]  O. G. Duliu, L. C. Dinescu, and D. Skliros, “INAA study of the distribution of some major and trace elements in Greek limestones and marbles,” Journal of Trace and Microprobe Techniques, vol. 17, no. 2, pp. 165–175, 1999.
[16]  A. R. Bromfield, “Sulphur in northern Nigerian soils: the effects of cultivation and fertilization on total socilsulpur and sulphate pattern in soil profile,” Journal of Agriculture Science, vol. 78, pp. 465–470, 1972.
[17]  M. E. Mosugu, V. O. Chude, I. E. Esu, T. Kparmwang, and W. B. Malgwi, “Contents and profile distribution of three forms of free iron oxides in three ultisols and an Alfisol in Nigeria,” Communications in Soil Science and Plant Analysis, vol. 30, no. 7-8, pp. 1013–1024, 1999.
[18]  K. K. Deshmukh, Central Region Neutron Activation Analysis at GSI Laboratory, Geological Survey of India, Pune, India, 2000.
[19]  D. De Soete, R. Gijbels, and J. Hoste, Neutron Activation Analysis, John Wiley & Sons, London, UK, 1972.
[20]  Ehmann, W. D, and D. E. Vance, Radiochemistry and Nuclear Methods of Analysis, vol. 116 of Chemical Analysis: A Series of Monographs in Analytical Chemistry and Its Applications, John Wiley & Sons, New York, NY, USA, 1990.
[21]  J. Csikai, Handbook of Fast Neutron Generators, vol. 1-2, CRC Press, Boca Raton, Fla, USA, 1987.
[22]  K. Heydorn, Neutron Activation Analysis For Clinical Trace Element Research, vol. 1-2, CRC Press, Boca Raton, Fla, USA, 1984.
[23]  S. J. Parry, Activation Spectrometry in Chemical Analysis, vol. 119 of Chemical Analysis: A Series of Monographs in Analytical Chemistry and Its Applications, John Wiley & Sons, New York, NY, USA, 1990.
[24]  J. Tolgyessy and E. H. Klehr, Nuclear Environmental Chemical Analysis, Series in Analytical Chemistry, Ellis Horwood, Chichester, UK, 1987.
[25]  J. Tolgyessy and M. Kyrs, Radioanalytical Chemistry, vol. 1-2, Ellis Horwood, Cichester, UK, 1989.
[26]  I. M. Klthoff and P. J. Elving, “Nuclear activation and radioisotope methods of analysis,” in Treatise on Analytical Chemistry, John Wiley & Sons, New York, NY, USA, 1986.
[27]  E. Witkowska, K. Szczepaniak, and M. Biziuk, “Some applications of neutron activation analysis: a review,” Journal of Radioanalytical and Nuclear Chemistry, vol. 265, no. 1, pp. 141–150, 2005.
[28]  I. O. Abugassa, S. Sarmani, and U. El-Ghawi, “Instrumental neutron activation analysis based on k0-standardization method as compared with other methods in the analysis of the IAEA inter-comparison test,” Journal of Radioanalytical and Nuclear Chemistry, vol. 259, no. 3, pp. 381–384, 2004.
[29]  J. H. Chao, Y. C. Sun, C. J. Chen, C. L. Tseng, and M. H. Yang, “Determination of trace Al in silicon carbide by epithermal neutron activation,” Applied Radiation and Isotopes, vol. 62, no. 4, pp. 561–567, 2005.
[30]  S. A. Jonah, I. M. Umar, M. O. A. Oladipo, G. I. Balogun, and D. J. Adeyemo, “Standardization of NIRR-1 irradiation and counting facilities for instrumental neutron activation analysis,” Applied Radiation and Isotopes, vol. 64, no. 7, pp. 818–822, 2006.
[31]  R. H. Filby, “Neutron Activation Analysis, Isotopic and nuclear analytical techniques in biological systems: a critical study, part IX,” Pure and Applied Chemistry, vol. 67, no. 11, pp. 1929–1941, 1995.
[32]  W. Liyu, WINSPAN (2004), A Multi-Purpose Gamma-Ray Spectrum Analysis Software, CIAE, Beijing, China, 2004.
[33]  R. L. Njinga, S. A. Jonah, I. O. B. Ewa, M. O. A. Oladipo, and G. A. Agbo, “Alternative approach for efficiency data generation in neutron activation analysis,” International Journal of Applied Science and Technology, vol. 1, no. 5, pp. 244–256, 2011.
[34]  E. E. Schulte, Soil and Applied Iron, Understanding Plants Nutrients A3554, 2000.
[35]  M. O. A. Oladipo, R. L. Njinga, A. Baba, and H. L. Muhammad, “Evaluation of trace elements in some northern-Nigeria traditional medicinal plants using INAA technique,” Applied Radiation and Isotopes, vol. 70, no. 6, pp. 917–921, 2012.
[36]  E. Epstein, Mineral Nutrition of Plants: Principles and Perspectives, John Wiley & Sons, New York, NY, USA, 1972.
[37]  H. D. Chapman, Ed., Diagnostic Criteria For Plants and Soils, University of California, Riverside, Calif, USA, 1972.
[38]  I. Pais, M. Fehér, E. Farkas, Z. Szabó, and I. Cornides, “Titanium as a new trace element,” Communications in Soil Science and Plant Analysis, vol. 8, pp. 407–410, 1977.
[39]  A. M. Ure and J. R. Bacon, “Comprehensive analysis of soils and rocks by spark-source mass spectrometry,” The Analyst, vol. 103, no. 1229, pp. 807–822, 1978.
[40]  V. Romheld and H. Marscher, “Function of micronutrients in plants,” in Micronutrients in Agriculture, J. Mortredt, F. R. Cox, L. M. Shuman, and R. M. Welch, Eds., Soil Science Society of America, Madison, Wis, USA, 1991.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133