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A simple formal stereoselective synthesis of Herbarumin IIIDOI: 10.5155/eurjchem.3.3.337-339.609 Keywords: Nonenolide , Phytotoxic effect , Syn-epoxy alcohol , Maruoka allylation , Trimethylsulfonium iodide , Diastereoselective iodine-induced electrophilic cyclization Abstract: A formal stereoselective synthesis of Herbarumin III has been accomplished starting from butanal involving Maruoka asymmetric allylation, diastereoselective iodine-induced electrophilic cyclization and conversion of iodocarbonate into syn-epoxy alcohol as the key steps.
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