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OALib Journal期刊
ISSN: 2333-9721
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A Common Approach to the Synthesis of Monocyclofarnesyl Sesquiterpenes

Keywords: Baeyer-Villiger reaction , monocyclofarnesyl , sesquiterpenes , aplysistatin , ambilol , 7-hydroxy-6 , 11-cyclofarnes-3(15)-en-2-one , ancistrofuran , synthesis

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Abstract:

3beta-hydroxy-4,4,10beta-trimethyl-9-decalone and its dehydroxy analogue are useful intermediates whose Baeyer-Villiger oxidation and subsequent two-carbon homologation provides a quick entry into the monocyclofarnesyl skeleton. The synthetic approaches to a variety of sesquiterpenes are discussed.

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