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无机材料学报 2009
Corrosion Behavior of AlPO4 as Environmental Barrier Coating in Water Vapor EnviromentDOI: 10.3724/sp.j.1077.2009.00397 Keywords: environmental barrier coating£ AlPO4£ compatibility£ water vapor corrosion Abstract: AlPO4 was synthesized by a Sol-Gel method. Its coefficient of thermal expansion (CTE) was measured by dilatometer. Its corrosion behavior was tested in an environment of 50vol%H2O/50vol%O2 with a flow rate of 0.085cm/s at 1350 The phases and composition of the samples were analyzed by X-ray diffraction and Energy Dispersive Spectroscope. The microstructures of AlPO4 were characterized by Scanning Electron Microscope. The results indicate that the CTE of AlPO4 matches with that of C/SiC composites and its corrosion resistance is much better than that of SiC. However, the decomposition of AlPO4 at high temperatures is the main problem in the water vapor enviroment£ which will be accelerated in combination with silica.
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