全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
Sensors  2013 

Ratiometric Optical Temperature Sensor Using Two Fluorescent Dyes Dissolved in an Ionic Liquid Encapsulated by Parylene Film

DOI: 10.3390/s130404138

Keywords: temperature sensor, ionic liquid, fluorescent dye, Parylene on liquid deposition (PoLD)

Full-Text   Cite this paper   Add to My Lib

Abstract:

A temperature sensor that uses temperature-sensitive fluorescent dyes is developed. The droplet sensor has a diameter of 40 μm and uses 1 g/L of Rhodamine B (RhB) and 0.5 g/L of Rhodamine 110 (Rh110), which are fluorescent dyes that are dissolved in an ionic liquid (1-ethyl-3-methylimidazolium ethyl sulfate) to function as temperature indicators. This ionic liquid is encapsulated using vacuum Parylene film deposition (which is known as the Parylene-on-liquid-deposition (PoLD) method). The droplet is sealed by the chemically stable and impermeable Parylene film, which prevents the dye from interacting with the molecules in the solution and keeps the volume and concentration of the fluorescent material fixed. The two fluorescent dyes enable the temperature to be measured ratiometrically such that the droplet sensor can be used in various applications, such as the wireless temperature measurement of microregions. The sensor can measure the temperature of such microregions with an accuracy of 1.9 °C, a precision of 3.7 °C, and a fluorescence intensity change sensitivity of 1.0%/K. The sensor can measure temperatures at different sensor depths in water, ranging from 0 to 850 μm. The droplet sensor is fabricated using microelectromechanical system (MEMS) technology and is highly applicable to lab-on-a-chip devices.

References

[1]  Rush, R.S.; Cohen, A.S.; Karger, B.L. Influence of column temperature on the electrophoretic behavior of myoglobin and alpha-lactalbumin in high-performance capillary electrophoresis. Anal. Chem. 1991, 63, 1346–1350.
[2]  Barilero, T.; Le Saux, T.; Gosse, C.; Jullien, L. Fluorescent thermometers for dual-emission-wavelength measurements: Molecular engineering and application to thermal imaging in a microsystem. Anal. Chem. 2009, 81, 7988–8000.
[3]  Arata, H.F.; Low, P.; Ishizuka, K.; Bergaud, C.; Kim, B.; Noji, H.; Fujita, H. Temperature distribution measurement on microfabricated thermodevice for single biomolecular observation using fluorescent dye. Sens. Actuators B Chem. 2006, 117, 339–345.
[4]  Kim, H.J.; Kihm, K.D.; Allen, J.S. Examination of ratiometric laser induced fluorescence thermometry for microscale spatial measurement resolution. Int. J.Heat Mass Transfer 2003, 46, 3967–3974.
[5]  Ross, D.; Gaitan, M.; Locascio, L.E. Temperature measurement in microfluidic systems using a temperature-dependent fluorescent dye. Anal. Chem. 2001, 73, 4117–4123.
[6]  Iles, A.; Fortt, R.; de Mello, A.J. Thermal optimisation of the reimer-tiemann reaction using thermochromic liquid crystals on a microfluidic reactor. Lab Chip 2005, 5, 540–544.
[7]  Uchiyama, S.; Matsumura, Y.; de Silva, A.P.; Iwai, K. Fluorescent molecular thermometers based on polymers showing temperature-induced phase transitions and labeled with polarity-responsive benzofurazans. Anal. Chem. 2003, 75, 5926–5935.
[8]  Sato, Y.; Irisawa, G.; Ishizuka, M.; Hishida, K.; Maeda, M. Visualization of convective mixing in microchannel by fluorescence imaging. Meas. Sci. Technol. 2003, 14, 114–121.
[9]  Nguyen, B.-K.; Kiyoshi, M.; Isao, S. Polymer thin film deposited on liquid for varifocal encapsulated liquid lenses. Appl. Phys. Lett. 2008, doi:10.1063/1.2988467.
[10]  Binh-Khiem, N.; Matsumoto, K.; Shimoyama, I. Tensile film stress of parylene deposited on liquid. Langmuir 2010, 26, 18771–18775.
[11]  Coppeta, J.; Rogers, C. Dual emission laser induced fluorescence for direct planar scalar behavior measurements. Exp. Fluid. 1998, 25, 1–15.
[12]  Sakakibara, J.; Adrian, R.J. Whole field measurement of temperature in water using two-color laser induced fluorescence. Exp. Fluid. 1999, 26, 7–15.
[13]  Aoki, H.; Binh-Khiem, N.; Kan, T.; Matsumoto, K.; Shimoyama, I. Functionalized Micro Bead with Liquid-Core Parylene-Shell Structure. Proceedings of the IEEE 25th International Conference on Micro Electro Mechanical Systems, Paris, France, 29 January–2 February 2012; pp. 831–834.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133