La 55Al 25Cu 10Ni 10 metallic glass has been reinforced with 325-mesh Ta particles to obtain ex situ glass-crystal composites. The composites show a high compressive plasticity (40%) with a minor reduction (~8%) in yield strength—a combination unprecedented for La-based systems and even surpassing some Zr-based glassy composites that utilize a tougher matrix. However, it is also found that the plastic strain is apparently sensitive to defects, like oxides, in the glassy matrix.
References
[1]
Xi, X.K.; Zhao, D.Q.; Pan, M.X.; Wang, W.H.; Wu, Y.; Lewandowski, J.J. Fracture of brittle metallic glasses: Brittleness or plasticity. Phys. Rev. Lett. 2005, 94, 125510–125513.
[2]
Lewandowski, J.J.; Wang, W.H.; Greer, A.L. Intrinsic plasticity or brittleness of metallic glasses. Philos. Mag. Lett. 2005, 85, 77–87, doi:10.1080/09500830500080474.
[3]
Choi-Yim, H.; Conner, R.D.; Szuecs, F.; Johnson, W.L. Processing, microstructure and properties of ductile metal particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites. Acta Mater. 2002, 50, 2737–2745, doi:10.1016/S1359-6454(02)00113-1.
Hays, C.C.; Kim, C.P.; Johnson, W.L. Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 2000, 84, 2901–2904, doi:10.1103/PhysRevLett.84.2901.
Hufnagel, T.C.; Fan, C.; Ott, R.T.; Li, J.; Brennan, S. Controlling shear band behavior in metallic glasses through microstructural design. Intermetallics 2002, 10, 1163–1166, doi:10.1016/S0966-9795(02)00157-7.
[8]
Qin, C.; Zhang, W.; Kimura, H.; Inoue, A. Excellent mechanical properties of Cu-Hf-Ti-Ta bulk glassy alloys containing in situ dendrite Ta-based BCC phase. Mater. Trans. JIM 2004, 45, 2936–2940, doi:10.2320/matertrans.45.2936.
[9]
Bian, Z.; Kato, H.; Qin, C.; Zhang, W.; Inoue, A. Cu-Hf-Ti-Ag-Ta bulk metallic glass composites and their properties. Acta Mater. 2005, 53, 2037–2048, doi:10.1016/j.actamat.2005.01.015.
[10]
Xu, Y.K.; Ma, H.; Xu, J.; Ma, E. Mg-based bulk metallic glass composites with plasticity and gigapascal strength. Acta Mater. 2005, 53, 1857–1866, doi:10.1016/j.actamat.2004.12.036.
[11]
Kinaka, M.; Kato, H.; Hasegawa, M.; Inoue, A. High specific strength Mg-based bulk metallic glass matrix composite highly ductilized by Ti dispersoid. Mater. Sci. Eng. A 2008, 494, 299–303, doi:10.1016/j.msea.2008.04.039.
[12]
Lee, M.L.; Li, Y.; Schuh, C.A. Effect of a controlled volume fraction of dendritic phases on tensile and compressive ductility in La-based metallic glass matrix composites. Acta Mater. 2004, 52, 4121–4131, doi:10.1016/j.actamat.2004.05.025.
[13]
Zhang, Y.; Xu, W.; Tan, H.; Li, Y. Microstructure control and ductility improvement of La-Al-(Cu,Ni) composites by Bridgman solidification. Acta Mater. 2005, 53, 2607–2616, doi:10.1016/j.actamat.2005.02.020.
[14]
Nagendra, N.; Ramamurty, U.; Goh, T.T.; Li, Y. Effect of crystallinity on the impact toughness of a La-based bulk metallic glass. Acta Mater. 2000, 48, 2603–2615, doi:10.1016/S1359-6454(00)00052-5.
[15]
Basu, J.; Nagendra, N.; Li, Y.; Ramamurty, U. Microstructure and mechanical properties of a partially crystallized La-based bulk metallic glass. Philos. Mag. 2003, 83, 1747–1760, doi:10.1080/0141861861031000104163.
[16]
Madge, S.V.; Sharma, P.; Louzguine-Luzgin, D.V.; Greer, A.L.; Inoue, A. New La-based glass-crystal ex situ composites with enhanced toughness. Scr. Mater. 2010, 62, 210–213, doi:10.1016/j.scriptamat.2009.10.029.
[17]
Massalski, T.B.; Okamoto, H.; Subramanian, P.R.; Kacprzak, L. Binary Alloy Phase Diagrams; ASM International: Cleveland, OH, USA, 1990; Volume 3, pp. 2427–2429.
[18]
Leonhard, A.; Xing, L.Q.; Heilmaier, M.; Gebert, A.; Eckert, J.; Schultz, L. Effect of crystalline precipitations on the mechanical behavior of bulk glass forming Zr-based alloys. Nanostruct. Mater. 1998, 10, 805–817, doi:10.1016/S0965-9773(98)00117-2.
[19]
Lu, Z.P.; Bei, H.; Wu, Y.; Chen, G.L.; George, E.P.; Liu, C.T. Oxygen effects on plastic deformation of a Zr-based bulk metallic glass. Appl. Phys. Lett. 2008, 92, 011915:1–011915:3.
[20]
Madge, S.V.; Wada, T.; Louzguine-Luzgin, D.V.; Greer, A.L.; Inoue, A. Oxygen embrittlement in a Cu-Hf-Al. Scr. Mater. 2009, 61, 540–543, doi:10.1016/j.scriptamat.2009.05.018.
[21]
Madge, S.V.; Louzguine-Luzgin, D.V.; Lewandowski, J.J.; Greer, A.L. Toughness, extrinsic effects and Poisson’s ratio of bulk metallic glasses. Acta Mater. 2012, 60, 4800–4809, doi:10.1016/j.actamat.2012.05.025.