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The 'Instrumental' Reality of PhlogistonKeywords: philosophy of chemistry , eighteenth-century chemistry , Sulphur Principle , Fire , Phlogiston , affinity table Abstract: The stability of phlogiston in eighteenth-century French chemistry depended not on its role as a comprehensive theory, but on its operational (instrumental), theoretical, and philosophical (speculative) identities that were forged in different contexts, yet were interwoven to designate a single substance. It was as 'real' as any other chemical substance to the degree that it was obtained through material operations, occupied a place in the theoretical edifice of the affinity table, and was endowed with a corpuscular ontology. Lavoisier labeled it as an 'imaginary' substance because it offered a unique resistance to his vision of the new chemistry based on 'metric' measurements and algebraic representations.
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