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Solvent effect on the spectral properties of Neutral Red

DOI: 10.1186/1752-153x-2-19

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Abstract:

The results have shown that the absorption maxima of dyes are dependent on solvent polarity. In non-hydrogen-bond donating solvents, solvation of dye molecules probably occurs via dipole-dipole interactions, whereas in hydrogen-bond donating solvents the phenomenon is more hydrogen bonding in nature. To estimate the contribution of the different variables on the wave number of the Neutral Red dye, regression analyses using the ECW model were compared with the π* scale model. This showed that the unified scale for estimating the solvent effect on the absorption of the Neutral Red dye is more adopted and more applicable than the π* scale model.Absorption maxima of dyes are dependent on solvent polarity. Solvation of dye molecules probably occurs via dipole-dipole interactions in non-hydrogen-bond donating solvents, whereas in hydrogen-bond donating solvents the phenomenon is more hydrogen bonding in nature. The unified scale for estimating the solvent effect on the absorption of Neutral Red dye is more adopted and more applicable than the π* scale model. This may be due to complications from both π-π* charge transfer interactions and incomplete complexation of the solute; these effects are averaged out in the derived β and π parameters and thus limit their applicability.It is very well known that chemical processes are influenced by the properties of solvents in which they are carried out. These include the dipole moment, dielectric constant, and refractive index values. The most important property in this regard is the solvent polarity which can change the position of the absorption or emission band of molecules by solvating a solute molecule or any other molecular species introduced into the solvent matrix. A number of literature citations are available for the studies of simple organic molecules with regard to their interactions in different solvents [1-3]. Dye molecules on the other hand are complex organic molecules which might carry charge centers (as an integra

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