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Poly[ethylenediammonium [tris[μ3-hydrogenphosphato(2−)]dicadmium] monohydrate]

DOI: 10.1107/s1600536810038729

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Abstract:

The title compound, {(C2H10N2)[Cd2(HPO4)3]·H2O}n, was synthesized under hydrothermal conditions. The structure of this hybrid compound consists of CdO6, CdO5 and PO4 polyhedra arranged so as to build an anionic inorganic layer, namely [Cd2(HPO4)3]2 , parallel to the ab plane. The edge-sharing CdO6 octahedra form infinite chains running along the a axis and are linked by CdO5 and PO4 polyhedra. The ethylenediammonium cation and the water molecule are located between two adjacent inorganic layers and ensure the cohesion of the structure via N—H...O and O—H...O hydrogen bonds.

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