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OALib Journal期刊
ISSN: 2333-9721
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catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride]

DOI: 10.1107/s1600536811055619

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Abstract:

In the title complex, {[Nd(C6H4NO2)2(H2O)4]Cl}n, the NdIII cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water molecules in a distorted square-antiprismatic geometry. The carboxylate groups of the isonicotinate anions bridge the NdIII cations, forming polymeric chains running along the c axis. The Cl anion is located on a twofold rotation axis and is linked to the polymeric chains via O—H...Cl hydrogen bonding. Intermolecular O—H...O and O—H...N hydrogen bonds are also present in the crystal structure.

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