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OALib Journal期刊
ISSN: 2333-9721
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{4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II)

DOI: 10.1107/s1600536812009397

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Abstract:

In the title compound, [Cu(C19H16Br4N2O2)], the CuII ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuII ion is distorted square-planar, which is defined by the N2O2 donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an intermolecular π–π interaction [centroid–centroid distance = 3.8891 (18) ].

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